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Meeting 2025 TMS Annual Meeting & Exhibition
Symposium Magnesium Technology 2025
Presentation Title Vacancy-Induced Solute Clustering in Binary Magnesium Alloys
Author(s) Sreenivas Raguraman, Zehao Li, Homero Reyes Pulido, Michael Falk, Arun Devaraj, Timothy Weihs
On-Site Speaker (Planned) Sreenivas Raguraman
Abstract Scope Vacancies in metals drive solute diffusion and clustering, impacting microstructure and alloy performance. This study explores how alloying elements and quenching from homogenization temperatures influence vacancy-induced solute clustering in Mg alloys. We investigate Mg-Al, Mg-Zn, and Mg-Y alloys, homogenized and quenched from 450°C to retain excess vacancies. Positron Annihilation Spectroscopy (PAS) quantifies vacancy concentrations, while Atom Probe Tomography (APT) maps solute clusters. Scanning Electron Microscopy (SEM) and XRD provide additional insights, complemented by Molecular Dynamics (MD) simulations for atomic-scale understanding. Initial results show pronounced clustering in Mg-Al and Mg-Zn alloys. This study highlights the role of alloy chemistry in vacancy-driven clustering, offering a framework to tune Mg alloy microstructures for structural and biomedical applications, where controlled clustering enhances mechanical and corrosion properties.
Proceedings Inclusion? Planned:
Keywords Magnesium, Characterization, Mechanical Properties

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Correlation of r-Value With Texture and Formability in Magnesium Alloy Sheets
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Dilute Mg Alloys Comprised of Earth-Abundant Elements With High Strength Imparted by Thermomechanical Processing
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Effect of Subsequent Heat Treatment on Microstructure, Hardness and Corrosion Behavior of Extruded and Swaged Mg0.15Ca
Effect of Zn or Ca Addition on Microstructure and Mechanical Properties of Mg-Ti Composites Fabricated Through Liquid Metal Dealloying
Effects of Zn and Ca Microalloying on β-Series Precipitation in Mg-Nd Alloys a Comparison of Electron Microscopy and Small-Angle Scattering Techniques
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Experimental and Computational Studies of Recrystallization in the Mg-Zn-Ca Alloy System
Experimental Investigation on Twinning Behavior in Mg-Y Alloys
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K-18: Comparative Studies on Corrosion of Short Fibre-Reinforced Mg Composites With and Without PEO Coatings
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