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Meeting MS&T23: Materials Science & Technology
Symposium 15th Symposium on Green and Sustainable Technologies for Materials Manufacturing and Processing
Presentation Title O-2: Effect of Heating Rate during Sulfurization on the Growth of Ethanol Based Solution Processed Cu2ZnSnS4 Thin Films
Author(s) Rahul Jain, Indu Gupta, Bhaskar Chandra Mohanty
On-Site Speaker (Planned) Rahul Jain
Abstract Scope Recently, Cu2ZnSnS4 (CZTS) has evolved as a very promising absorber material for thin film solar cells. The low cost, environmental harmless and earth abundant constituents of Cu2ZnSnS4 (CZTS) possesses promising characteristic optical properties. While hydrazine based solution processed films have yielded the highest efficiency of ~12.6%, the toxic and carcinogenic nature of hydrazine offsets the advantages. In the context of on-going worldwide research on solution based processing, sulfurization process has been found to be crucial to efficient device performance. In this work, we have prepared phase pure kesterite CZTS thin films of appropriate thickness by chemical bath deposition technique from ethanol-based precursor solution followed by sulfurization at 500 °C. The films were characterized by a variety of techniques. The sulfurization process dependant growth of CZTS thin films was studied.

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Coke Gasification Pulverization and Carbon Bearing Powder Characteristics in a Blast Furnace
Computational Methods for Designing Effective Compatibilizers for Recycled Polymer Blends
Corrosion Resistant Coatings on Steel for Nuclear Energy Applications
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Fabrication and Material Properties of Silicon Nitride Bearing Grade Balls for Hybrid Ball Bearing Applications.
Factors Affecting the Thermal Conductivity of Liquid-phase Sintered Silicon Carbide Ceramics
Green Synthesis of Calcium Molybdate Using Bimetallic Precursors
Little Known Nylon: Bio-Based Feedstocks and Synthesis for Nylon 5,9
Molten Oxide Electrolysis for Reducing the Carbon Footprint of Technology-critical Metals
Nanoclays in Biomaterials Design: From Regenerative Medicine to Invitro Disease Models
O-1: Briquetting Waste Glass Fines to Enable Recycling
O-2: Effect of Heating Rate during Sulfurization on the Growth of Ethanol Based Solution Processed Cu2ZnSnS4 Thin Films
O-3: Facile Growth of Cu2ZnSn(SSe)4 Thin Films with Controlled Phase and Microstructure from Ethanol Based Molecular Solutions
O-4: Mesoporous Silica Material with Yolk Shell Morphology for Effective Removal of Environmental Pollutants
O-5: Rapid Method Development and Optimization for Environmental Monitoring by Gas Chromatography Using ProEZGC – A Free Web-based Software
O-6: Response of Ghana’s Akokorowa Iron Ore to Reduction by Carbonaceous Material Generated from Pyrolytic Chars of End-of-Life Tyres
Recycling Strategies for End-of-Life Solid Oxide Cell Materials
Strategies for Patenting "Green" Technologies
Structure and Stability of Cement-Zeolite Systems for Enhanced Carbon Uptake in Ambient Conditions
Synthesis of a Novel Cuprate with Gold under a High Oxygen Partial Pressure
The Investigation of an Energy-efficient Coking Technique Based on the Hot Tamping Operation
The Roles of Co and Ni Additions to High Solute Content Fe-contaminated Al Alloys in Beneficing Microstructure and Tensile Properties
Transparent Yttria Ceramics Fabricated Using Direct Ink Writing Printing and Vacuum Sintering

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