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Meeting 2020 TMS Annual Meeting & Exhibition
Symposium Phase Stability, Phase Transformations, and Reactive Phase Formation in Electronic Materials XIX
Presentation Title Learning from the Ni3Sn2 for Cu6Sn5
Author(s) Andreas Leineweber, Christian Wieser, Werner Hügel
On-Site Speaker (Planned) Andreas Leineweber
Abstract Scope Eta-Cu6Sn5 is one of the main intermetallic phases forming during soldering of Cu base alloys using Sn base solders. It is based on a Ni2In/NiAs type, where differently ordered states have been reported for Cu6Sn5 (or “Cu5Sn4”), have, however, only incompletely reconciled with the Cu-Sn phase diagram. We present new details on the Cu-Sn phase diagram, especially as determined from precisely measured lattice parameter data of Cu6Sn5 in its ordered and disordered state. This reveals insight on the compositions of the differently ordered states. The observations are, in particular, compared with findings for structurally similar Ni3Sn2 from the Ni-Sn system. In contrast to Cu6Sn5, that Ni-Sn intermetallic has a wide homogeneity range with pronounced structural effects due to the different ordered states. These differences makes Ni3Sn2 a good model system to study effects, which are much more subtle in Cu6Sn5.
Proceedings Inclusion? Planned: Supplemental Proceedings volume

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

4D Characterization of Electromigration-induced Grain Boundary Damage of Cu Interconnects: X-ray Tomography Experiments and Phase-field Simulations
An Ab-initio Study on the Structural and Electrochemical Propeties of Na3V2(PO4)2F3 as Cathode Materials for Hybrid-ion Batteries
CALPHAD-assisted Analyses of BOF Slag Modification and Reduction
Challenges and Solutions for Experimental Investigation of Air and Moisture Sensitive Li Alloys
D-10: A Switching Model of Phase-change Memory by Combining Electrothermal and Phase-field Models
D-11: CALPHAD-assisted Analyses of BOF Slag Recovery
D-12: Comparison of Oxide Reduction Temperature between Highly <111>-Oriented Nanotwinned Cu and Regular Cu Films
D-13: Effects of Current Stressing on Mechanical Property and Microstructure of an Fe-Ni Alloy at Ambient Temperature
D-14: Effects of Plating Current Density on the Microstructure of Cu Pillars and Its Solderability
D-15: Effects of Surface Finish on the Interfacial Cu6Sn5 Morphology and Mechanical Characteristics in Solder Joints
D-16: From Electric Current-induced Lattice Strain to Electromigration Occurrence: An In-situ Study
D-17: Interfacial Reaction of Au-xAg/Al Couples
D-18: Interfacial Reactions in the Au/Sn-xZn/Cu Sandwich Couples
D-19: Interfacial Reactions in the Cu/Sn/Ni Sandwich Couples
D-20: Interfacial Reactions in the Sn/Au-xCu Couples
D-21: Interfacial Reactions of Ag-Au-xPd Alloys Wire Bonding with Al
D-22: Mechanisms of Abnormal Grain Growth of Al Bonding Wires under Annealing Process
Effects of Copper Electroplating Parameters on the Copper-based Solder Joint Reactions
Effects of Pd(P) Thickness on the Interfacial Reaction and Mechanical Properties of the Sn-3.5Ag/Au/Pd(P)/Ni(P) Microelectronic Joints
Electromigration Effect Upon Single-phase and Two-phase Ag-Cu Alloy: an In-situ Study
Electroplating of Rhodium using Pulse Current Plating Method
Full Battery Design for Li-ion Batteries Using CALPHAD Technique
High-throughput CALPHAD-type Calculation in Design of Coherent Precipitate-strengthening AlCuFeNiTi Multi-principal Element Alloys
In-situ Study of Electrochemical Migration of Tin in Presence of Contaminants
Interfacial Reaction in the Lead-free Solder/Cu-2.0Be (Alloy 25) Couples
Interfacial Reactions between Lead-free Solders and Electroless Co(B) Metallization
Interfacial Stability between High-temperature Lead-free Solders and Substrates
Investigation of Metal Filament Formation
Learning from the Ni3Sn2 for Cu6Sn5
Microstructure of Cu/Cu Joints using Sn-Coated Cu Particle Paste for High-temperature Application
Real-time Observation of the Accelerated Growth of (Cu,Ni)6Sn5 on Cu-xNi Current Collectors
Revisit the Blech Critical Product: Lattice Strain Induces Electromigration Effect
Study on Eelectromigration of Cu-Sn IMC Formation Due to Currents Stress and Temperature
Study on the Phase Diagrams of Bi-Te Binary and Bi-Te-RE (Yb, La, Ce, Nd, Sm, Tb, Er) Ternary Systems
The Effect of the Cu Preferred Orientation on the Adhesion between Cu and LCP in FCCL
Thermodynamic Modeling of the Cu-Mg-Si-Sn Quaternary System and Interpretation of Mg2(Si0.3Sn0.7)/Cu Thermoelectric Interconnections
Wafer Level SLID Bonding - Formation and Evolution of Microstructures
Zn Whisker Growth under High Temperature and Humidity Conditions

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