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Meeting 2025 TMS Annual Meeting & Exhibition
Symposium Phase Stability, Phase Transformations, and Reactive Phase Formation in Electronic Materials XXIV
Presentation Title Solid/Solid Interfacial Reactions Between Lead-Free Solders and Cu-Ni-Si-Mg (C7025) Substrate
Author(s) Ting Chen, Jing-Ting Chou, Yee-Wen Yen
On-Site Speaker (Planned) Ting Chen
Abstract Scope The solid/solid reaction couple technique was employed to investigate the interfacial reactions between the Cu-3.0 wt.% Ni-0.65 wt.% Si-0.15 wt.% Mg (C7025) substrate and lead-free solders (LFS)-Sn, and Sn-3.0 wt.% Ag-0.5 wt.% Cu (SAC) at 125, 150, and 175°C for 96 to 1536 h. The η'-Cu6Sn5 phase near the solder and the (Cu, Ni)6Sn5 phase close to C7025 substrate were formed in all couples. No Cu3Sn phase was found at the LFS/C7025 interface. The thickness of the intermetallic compounds (IMCs) increased with the increase in the reaction times and temperatures. However, the thicker IMC layer was observed in the SAC/C7025 couple. The cracks observed at the LFS/C7025 interface due to the mismatch in the coefficient of thermal expansion between the (Cu, Ni)6Sn5 phase and C7025 substrate. Meanwhile, the cracks were observed among the η'-Cu6Sn5 phases attributed to the stress from the IMC growth.
Proceedings Inclusion? Planned:
Keywords Electronic Materials, Phase Transformations, Other

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Bonding Mechanism for Cu/SiO2 Hybrid Joints
Computational Simulation of Interfacial Bonding Behavior with Various Grain Structures in Cu-Cu Bonding
Effect of Copper Grain Size on Interfacial Reactions of Copper/Solder/Copper Sandwiched Joints
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In-situ Characterization of Electrical Current Induced Structural Changes in Single-Phase η-Cu6Sn5 Using Synchrotron Radiation
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Microstructural Analysis and Mechanical Properties Evaluation of Zinc-Coated Aluminum Particles
Microstructure Evolution and Growth Behavior of Intermetallic Compound Between Cu and Sn-Ag Alloys
Microstructure Evolution and Phase Transformation of Ni-Sn Compounds aAfter Long-Term Storage
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Striped Strain-Induced Coherency Loss Leading to Metastable Nanoprecipitate Phase Transformation in Al-Zn-Mg Alloys
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The Effect of Temperature on the Microstructure, Lattice, Mechanical and Electrical Properties of Sn-Bi Alloys

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