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Meeting 2024 TMS Annual Meeting & Exhibition
Symposium Environmental Degradation of Multiple Principal Component Materials
Presentation Title B-2: Elemental Affinity Engineering for Improving Hydrogen Embrittlement in CoCrFeNiV High-entropy Alloys
Author(s) Sang Yoon Song, Gunjick Lee, Dae Cheol Yang, Min Young Sung, Yuri Hur, KenHee Ryou, Hyeon-Seok Do, Aparna Saksena, Baptiste Gault, Byeong-Joo Lee, Won-Seok Ko, Se-Ho Kim, Seok Su Sohn
On-Site Speaker (Planned) Sang Yoon Song
Abstract Scope Hydrogen embrittlement (HE) is a significant concern as it leads to reduction in the mechanical properties of metals and alloys. Previous research on HE has primarily focused on investigating microstructural factors and mitigating HE through microstructural modifications. However, there are limitations to improving HE solely through changes in microstructure, as it directly influences mechanical properties. To overcome these limitations, utilization of elements with hydrogen affinity, which can potentially alter hydrogen trap and diffusion behavior, offers promising approach. Nevertheless, studies addressing improvement of HE through hydrogen affinity have been lacking. In this study, two Fe-based high-entropy alloys were designed by selectively replacing V and Ni to have martensite matrix with 10% retained FCC. The V-added alloy having high hydrogen affinity exhibited significant enhancement in HE, accompanied by increase in hydrogen content and decrease in hydrogen diffusivity. The role of high-affinity V was confirmed based on the cryogenic atom probe tomography analysis.
Proceedings Inclusion? Planned:
Keywords High-Entropy Alloys, Environmental Effects, Mechanical Properties

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Accelerating the Design and Discovery of Tribocorrosion-resistant Metals by Interfacing Multiphysics Modeling With Machine Learning and Genetic Algorithms
Advanced Studies of Radiation Damage in Compositionally Complex Alloys
Aloe Saponaria Gel as a Green Corrosion Inhibitor of Carbon Steel in an Acid Médium
B-1: A High Throughput CALPHAD Method of Designing Low Density, Compositionally-complex Alloys Toward Understanding Lightweighting Elements' Effects on Passivity
B-2: Elemental Affinity Engineering for Improving Hydrogen Embrittlement in CoCrFeNiV High-entropy Alloys
B-3: High Temperature Oxidation of HEAs and NC-strengthened HEAs in Presence of Water Vapor
B-4: Investigation of Mechanical Stress and B10 Exposure on FKM Polymer
Behavior in Cooling–induced Oxide Scale Spallation of Original and Modified Cantor’s HEA Alloys Oxidized at High Temperature
Bottom-up versus Top-down Oxide Scale Design in Refractory High Entropy Alloys
Combinatorial Synthesis of Non-equiatomic CrMoNbTaW With Improved Strength and Oxidation Resistance
Comparison of Initial-stage High Temperature Oxidation Behavior of MCrAlY and Hf-Y Co-doped CoCrFeNiAl Complex-concentrated Alloy in Wet Air
Corrosion Resistance of 316L Stainless Steel in Hydrochloric Acid
Cracking the Code: Demystifying Early-stage Oxidation in High Entropy Alloys
Deformation Behavior of High Entropy Alloys as a Function of Strain Rate and Temperature
Development of Novel Light Refractory High Entropy Alloys for High Energy Accelerator Windows
Effects of Varying Al Content on the Microstructure of the Fe-Cr-Ni-Mn-Al Multi-component Alloy System
Environmental Degradation of Polymer-based Composite Materials: Challenges and Mitigation Strategies
Environmental Impact of Multi-component Fiber-reinforced Composites: Challenges and Green Solutions
Evaluation of a Nb-Si-Ti-Al-Hf Alloy as a Bond Coat for Nb-based Alloys
Exploring the Synergy of Al-Cr in Aqueous Passivation of [FeCoNi]CrxAly Compositionally Complex Alloys (CCAs) Across Cr Threshold Concentrations
High-Entropy Alloys Corrosion Behaviors
High Entropy Alloys for Advanced Modular Reactors
Impaired Repassivation Kinetics of Multi-principal Element Alloy Surfaces Caused by Selective Oxidation and Nickel Enrichment
Initial Hot Corrosion Behavior of Graded Composition Transition Joints and Dissimilar Metal Weldments of P91&304 under Molten Sulfate Salts
Insights into Defects and Failure of Multi-component Ultra-high Temperature Carbides
Insights on the Oxidation Behavior of Refractory High Entropy Alloys
Irradiation and Oxidation Behavior of Multi-principal Element Alloys Manufactured by Different Techniques
Isothermal High Temperature Oxidation of Cantor’s–based MC–reinforced HEAs Versus Their Mn and Cr Contents
Orientation Dependency of Hydrogen-induced Cracks in Single-crystalline CrCoNi Medium-entropy Alloy
Oxidation of NiCoCr Alloys in High Temperature Air and Steam Environments
Simulations of Chloride on Hydroxylated Passive Oxide Surfaces Related to Localized Corrosion Initialization
Some Effects of Hydrogen on the CoCrFeMnNi Alloy
Study of the Corrosive Effect of Enzymatic, Multi-enzymatic, and Sodium Hypochlorite Solutions on Surgical-grade Stainless Steel Instruments Used in the Operating Room Area of the Clinical Hospital
Utilizing Small Punch Test (SPT) for Mechanical Behaviour Study of Electrochemically and Gaseous Hydrogenated Electron Beam Melting (EBM) and Wrought Ti–6Al–4V
Wear Behavior of Multi-component Ultra-high Temperature Carbides

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