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Meeting MS&T23: Materials Science & Technology
Symposium Thermodynamics of Materials in Extreme Environments
Presentation Title Stability and use of Nitride and Carbide Nuclear Fuels in Advanced Reactors and Nuclear Propulsion in Space
Author(s) Theodore Besmann, Ronald E Booth, Reece McManus, Juliano Schorne-Pinto, Jhonathan Rosales, Antoine Claisse
On-Site Speaker (Planned) Theodore Besmann
Abstract Scope Non-oxide nuclear fuels have seen renewed interest in the growing activities on advanced terrestrial power reactors, and once again for power production and nuclear thermal propulsion (NTP) in space. The current presentation will review the nature of nitride and carbide fuels and their potential in-reactor behavior. A design for a lead-cooled reactor utilizes UN because of its high uranium volumetric fraction and thermal conductivity. NTP systems are looking to heat hydrogen propellant to very high temperatures using UC-based fuel due to its high uranium mass fraction and thermal conductivity. The melting temperature of UC is too low to get the desired rocket impulse, and thus additional components such as ZrC, TaC, and NbC forming a solid solution with UC are being investigated. This presentation will discuss the results of assessing the phase equilibria and thermodynamics of UN fuel undergoing burnup and complex carbide fuel for NTP.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

ACerS Navrotsky Award: Thermodynamic Stability, Radiation Damage and Leaching Effects in Tunnel Structured Hollandite Materials
An Ab Initio Study of the Thermodynamic and Thermophysical Properties of Pu-bearing Salts
Deep Learning for Large-scale Prediction of Melting Temperature and Materials Properties
Determination of Mixing Enthalpy of La and U in Chloride Molten Salt
Exploring and Implementing Thermodynamic Models for Liquid and their Applications to Thermodynamic Modeling of Molten Salts
Formation of Carbon Nanotubes from Multilayered Graphene in Astrophysical Settings
Heat Capacity of Microgram Oxide Samples by Fast Scanning Calorimetry
J-6: Determination of the Activation Energy of the Formation of Intermetallic Compounds in the Ni-Al and Ti-Al System during Thermochemical Pressing
J-7: Effect of Temperature on the Solubility of Corrosion Products of Structural Materials in the Form of Spinels (Fe–Cr–Ni Systems)
J-8: Influence of pH of the Coolant, Concentration of Corrosion Products on the Rate of Formation of Deposits in the Internal Circuit Equipment of Power Units
J-9: Thermodynamic Properties of Special Alloys of the Ti-Al System Formed during Synthesis
Mixing Behaviors in Group IV and V Oxides and Diborides
Molecular Dynamics Simulations of the Structures and Transport properties of UCln (n=3, 4) in NaCl and MgCl2 Molten Salts
New Classes of Phase Diagrams for Materials in Extreme Environments
Stability and use of Nitride and Carbide Nuclear Fuels in Advanced Reactors and Nuclear Propulsion in Space
Thermochemistry of Co Transition Metal Nitrides
Thermodynamic and Kinetic Considerations of CMAS Reactions with Rare-earth Monosilicates
Thermodynamic Assessment of Ce3In by Experimental and Computational Methods
Thermodynamic Assessment of the MgCl2-NaCl-KCl-CsCl Pseudo-quaternary System for Calculation of Volatile Fission Product (Cesium) Behavior in Molten Chloride Reactors
Thermodynamic Modelling Possibilities of High-persistent (Thermally, Mechanically, Chemically) Functional Materials
Thermodynamics of Bicrystal Metal-oxide Interfacial Failure at High Temperature
Thermodynamics of Cr-alloy Coated Zr-alloy Cladding Systems
Thermodynamics of Molten Salts for the Fluoride Salt Cooled High-temperature Reactor

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