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Meeting MS&T23: Materials Science & Technology
Symposium Thermodynamics of Materials in Extreme Environments
Presentation Title Thermodynamics of Bicrystal Metal-oxide Interfacial Failure at High Temperature
Author(s) Shen J. Dillon
On-Site Speaker (Planned) Shen J. Dillon
Abstract Scope The mechanical response and failure of metal-oxide phase boundaries influence the performance of a variety of engineering systems. For example, spalling of environmental barriers affects the lifetime of refractory alloy turbine blades. Similarly, high temperature mechanical interactions between oxide nuclear fuels and metallic fuel cladding can influence the lifetime of fuel rods. The behavior of such interfaces is challenging to predict theoretically, and little experimental data exists to describe their properties. In this work, a series of metal-oxide bicrystal interfaces were loaded in tension to determine the criteria for interfacial failure in the regime where interfacial diffusion is facile. The experiments provide insights into interactions between the sintering stress, damage accumulation, and the failure stress.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

ACerS Navrotsky Award: Thermodynamic Stability, Radiation Damage and Leaching Effects in Tunnel Structured Hollandite Materials
An Ab Initio Study of the Thermodynamic and Thermophysical Properties of Pu-bearing Salts
Deep Learning for Large-scale Prediction of Melting Temperature and Materials Properties
Determination of Mixing Enthalpy of La and U in Chloride Molten Salt
Exploring and Implementing Thermodynamic Models for Liquid and their Applications to Thermodynamic Modeling of Molten Salts
Formation of Carbon Nanotubes from Multilayered Graphene in Astrophysical Settings
Heat Capacity of Microgram Oxide Samples by Fast Scanning Calorimetry
J-6: Determination of the Activation Energy of the Formation of Intermetallic Compounds in the Ni-Al and Ti-Al System during Thermochemical Pressing
J-7: Effect of Temperature on the Solubility of Corrosion Products of Structural Materials in the Form of Spinels (Fe–Cr–Ni Systems)
J-8: Influence of pH of the Coolant, Concentration of Corrosion Products on the Rate of Formation of Deposits in the Internal Circuit Equipment of Power Units
J-9: Thermodynamic Properties of Special Alloys of the Ti-Al System Formed during Synthesis
Mixing Behaviors in Group IV and V Oxides and Diborides
Molecular Dynamics Simulations of the Structures and Transport properties of UCln (n=3, 4) in NaCl and MgCl2 Molten Salts
New Classes of Phase Diagrams for Materials in Extreme Environments
Stability and use of Nitride and Carbide Nuclear Fuels in Advanced Reactors and Nuclear Propulsion in Space
Thermochemistry of Co Transition Metal Nitrides
Thermodynamic and Kinetic Considerations of CMAS Reactions with Rare-earth Monosilicates
Thermodynamic Assessment of Ce3In by Experimental and Computational Methods
Thermodynamic Assessment of the MgCl2-NaCl-KCl-CsCl Pseudo-quaternary System for Calculation of Volatile Fission Product (Cesium) Behavior in Molten Chloride Reactors
Thermodynamic Modelling Possibilities of High-persistent (Thermally, Mechanically, Chemically) Functional Materials
Thermodynamics of Bicrystal Metal-oxide Interfacial Failure at High Temperature
Thermodynamics of Cr-alloy Coated Zr-alloy Cladding Systems
Thermodynamics of Molten Salts for the Fluoride Salt Cooled High-temperature Reactor

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