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Meeting 2024 TMS Annual Meeting & Exhibition
Symposium Phase Stability, Phase Transformations, and Reactive Phase Formation in Electronic Materials XXIII
Presentation Title Active Metal Brazing for Fabricating Cu/Si3N4/Cu Substrates with Ag-Cu-Ti Pastes
Author(s) Shih-kang Lin, Chia-mei Chen, Shih-yuan Cheng, Chih-han Yang, Klinsmenn Pan, Megan Huang, Vincent Hsu
On-Site Speaker (Planned) Shih-kang Lin
Abstract Scope Substrates with efficient heat dissipation capability is required for the third-generation semiconductor, e.g., SiC and GaN, packages. Si3N4 possesses high thermal conductivity and is a promising insulating substrate material as compared with the conventional Al2O3 substrate. However, its bonding with Cu conducting pads cannot be simply done via the CuO and Al2O3 eutectic reaction. Herein, we utilized active metal brazing (AMB) process with Ag-Cu-Ti filler to fabricate Cu/Si3N4/Cu substrates, for which the interfacial voids were the main reliability concern. We systematically investigated the processing parameters as well as materials combinations. In the presentation, the void formation mechanism will be elaborated, and the cost-effective void mitigation strategy will be proposed. The fundamental understanding of AMB can be applied to other metal/ceramic joint systems, supporting the development of heterogeneous integration in electric vehicles, green energy, and high-power applications.
Proceedings Inclusion? Planned:

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A-27: Co/Bi2(Se,Te)3 Interfacial Reactions and Bi-Co-Se-Te Phase Equilibria
A-28: Cu Surface Protection Treatments for Anti-oxidation and Anti-corrosion
A-29: Efficiency Enhancement of P-I-N Perovskite Solar Cells by Self-assembled Silane Treatment of Hole Transporting Layer
A-30: Electric Current-induced Unexpected Phase Transition for the ƞ'-Cu6Sn5 Phase at Low Temperatures
A-31: Impurity Effects on Interfacial Reactions between Sn-Zn-based Solders and Electroplated Cu Films
A-32: Silver Nanoparticles Modified Polyimide Covalent Organic Frameworks Composites for Dye-sensitized Solar Cells
A-33: Study on the Stability of the Synergistic Inhibition Effect of Metal Ions and Nitrides on Copper Corrosion
A Comprehensive Study of Microstructure, Texture, and Properties Evolutions in Pure Metals Induced by Electric Current Stressing
Active Metal Brazing for Fabricating Cu/Si3N4/Cu Substrates with Ag-Cu-Ti Pastes
Ag and Cu Whiskers in the Ag-Cu-Se Ternary System
Bonding Strength of ENIG Joint Using Micro-sized Ag Particles with Submicron Ceramic Particles
Effective Suppression of Boron Dopant on the Interfacial Reactions of Electroplating Co(B) Deposits and Lead-free Solders
Effects of Bi and In on the Growth of Intermetallic Compounds
Effects of Storage Time on the Growth of Cu(In,Sn)2
Electric Current Effects on Stability and Mechanical Properties of Monoclinic Cu6Sn5 Phase Based on In-situ Nanoindentation
Electrochemically Based and Coupled Approaches for Tracking Phase Transformations in Energy Storage Materials
Evolution of Vibrational Modes during Antiferrodistortive Phase Transition in SrTiO3
Exploration of Gel Hardness by Using Machine Learning Method
Growth Kinetics and Morphological Evolution of Compounds in Cu-eutectic Sn-Bi Alloy System with Ag and Ni
Improvement of Microelectronic Joint Reliability through the Optimization of IMC Nanomechanical Properties
Improving Mechanical Properties of Eutectic Sn-Zn Low-Melting Alloy by Indium Addition
In-situ Study of Phase Transformation and Strain Localization in Multi-phase Alloys
Interfacial Reaction in the Liquid/Solid Lead-free Solder/Cu-Ni-Si-Mg Alloy (C7025) Couples
Microstructure and Strength of Sn-Ag-Cu Solder Joint Using Blue Diode Laser
Phase Equilibrium of Cu-Sn-Ti Ternary System at 450 ℃
Phase Stability and Binodal/Spinodal Decomposition of Ag- and S-alloyed CIGS Absorbers: An Ab Initio-assisted CALPHAD Study with Key Experiments
Properties and Phase Transformations of Manganese Oxides for Environmentally Friendly Batteries
Superplasticity Deformation of Sn-Bi Based Solder Alloys
The Effect of Nitrogen on the Stability of the β Phase in W Thin Films during Thermal Annealing
The Effect of Nitrogen on Thermomechanical Behavior during the β-α Phase Transformation in W Thin Films
X-ray Diffraction on Solder-related Intermetallic Phases

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