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Meeting MS&T22: Materials Science & Technology
Symposium Glasses and Optical Materials: Current Issues and Functional Applications
Presentation Title The Dissolution of Lithium Disilicate Glass under Ultrasonic Cavitation
Author(s) Ben Dillinger, Carlos Suchicital, David Clark
On-Site Speaker (Planned) Ben Dillinger
Abstract Scope There has been little research conducted on how ultrasonication may affect glass dissolution. The focus of this study was to examine how the mechanisms and kinetics of glass dissolution may change in a system under ultrasonication. Experiments were conducted on lithium disilicate glass in deionized water for between 1 and 7.5 hours at 50°C. Results indicated that the kinetics of glass dissolution were affected by erosion caused by cavitation created during ultrasonication. Samples with macroscopically visible erosion had ~2-3x more dissolution compared to samples without erosion. The change in dissolution was thought to be due to two processes. First, the erosion caused the surface area of the sample to volume of solution (SA/V) ratio to increase through the roughening of the surface and the release of particulates into solution. Second, the depleted layer was removed at a faster rate under ultrasonication than would normally be possible under static conditions.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

3D Mapping of Glass Indentation Stress Fields
Continuation of the Investigation of Double Ion-exchange in Mixed Alkali-lime Silicate Glasses
D-13: Flow Dissolution of Lithium Disilicate Glass under Aqueous Conditions
D-15: Natural Glasses – Findings from an Undergraduate Project
D-17: Sulfur Blue Glasses - S3- Anion Charge Transfer Transitions
D-18: Tungsten Borate – A Replacement for Lead in Glass
D-19: Unusual High Oxidation States of Transition Metal Ions in Silicate Glasses of High Optical Basicity: Trivalent Co3+ and Ni3+
Effect of Ion-exchange Strengthening on the Mechanical Behavior of Sodium Aluminophosphosilicate Glass
Effect of Modifier Cation Type on Structure and Nickel Speciation in Alkali Borosilicate Glasses
Glass Structure-Terahertz Properties Relationship: Power-Law Model and Deviations in Sodium Borosilicate, Tellurite, and Chalcogenide Glass Families
Intermediate-range Order in Organic Glasses
Ionic Glasses: An Emerging Separate Class of Amorphous Materials with Unique Topology and Dynamic Properties
Lithium-iron Silicate Glasses as Simulations of High-Fe Nuclear Waste Glass
MD Simulations of SLS Batch Melting
Multispectroscopic Study of Lead Borate Glasses
Oxygen Triclusters and Five-Coordinated Alumina Species in Calcium-aluminosilicate Glasses
Structural Relaxation Mechanism of Anisotropic Alkali Metaphosphate Glass
Structure-property Relationship in Mixed Oxy-sulfide Glassy Solid Electrolyte Material: 0.58Li2S + 0.42 [(1–y­)SiS2 + yLiPO3]
The Dissolution of Lithium Disilicate Glass under Ultrasonic Cavitation
The Problem with Lead
Uncovering Hidden Glasses
Utilizing Electrical Impedance Spectroscopy (E.I.S.) to Observe In-situ Phase Changes in Lithium Diborate Glass Undergoing Thermal Relaxation

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