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Meeting MS&T22: Materials Science & Technology
Symposium Glasses and Optical Materials: Current Issues and Functional Applications
Presentation Title Intermediate-range Order in Organic Glasses
Author(s) Fnu Spoogmay, Gang Chen
On-Site Speaker (Planned) Gang Chen
Abstract Scope Intermediate-range order (IRO) is a unique phenomenon of glasses. An important structural signature of the IRO is so-called first sharp diffraction peak (FSDP) that appears at a low scattering vector position (< 2Å-1) of the X-ray or neutron scattering patterns of the glasses. Although FSDP has been observed in many different glass systems, its structural origin remains elusive and seems to be specific to the individual glass systems. The IRO has been studied extensively in inorganic glasses but very few efforts have been dedicated to organic glasses. In this paper, we select a simple organic glass system (i.e., polyestyrene) as a model system to understand the effect of molecular weight and temperature on the FSDP. We also study the effect of radiation on the FSDP using neutron radiation generated from the 4.5-MV tandem accelerator at Ohio University. The effect of radiation dose on the FSDP will also be discussed.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

3D Mapping of Glass Indentation Stress Fields
Continuation of the Investigation of Double Ion-exchange in Mixed Alkali-lime Silicate Glasses
D-13: Flow Dissolution of Lithium Disilicate Glass under Aqueous Conditions
D-15: Natural Glasses – Findings from an Undergraduate Project
D-17: Sulfur Blue Glasses - S3- Anion Charge Transfer Transitions
D-18: Tungsten Borate – A Replacement for Lead in Glass
D-19: Unusual High Oxidation States of Transition Metal Ions in Silicate Glasses of High Optical Basicity: Trivalent Co3+ and Ni3+
Effect of Ion-exchange Strengthening on the Mechanical Behavior of Sodium Aluminophosphosilicate Glass
Effect of Modifier Cation Type on Structure and Nickel Speciation in Alkali Borosilicate Glasses
Glass Structure-Terahertz Properties Relationship: Power-Law Model and Deviations in Sodium Borosilicate, Tellurite, and Chalcogenide Glass Families
Intermediate-range Order in Organic Glasses
Ionic Glasses: An Emerging Separate Class of Amorphous Materials with Unique Topology and Dynamic Properties
Lithium-iron Silicate Glasses as Simulations of High-Fe Nuclear Waste Glass
MD Simulations of SLS Batch Melting
Multispectroscopic Study of Lead Borate Glasses
Oxygen Triclusters and Five-Coordinated Alumina Species in Calcium-aluminosilicate Glasses
Structural Relaxation Mechanism of Anisotropic Alkali Metaphosphate Glass
Structure-property Relationship in Mixed Oxy-sulfide Glassy Solid Electrolyte Material: 0.58Li2S + 0.42 [(1–y­)SiS2 + yLiPO3]
The Dissolution of Lithium Disilicate Glass under Ultrasonic Cavitation
The Problem with Lead
Uncovering Hidden Glasses
Utilizing Electrical Impedance Spectroscopy (E.I.S.) to Observe In-situ Phase Changes in Lithium Diborate Glass Undergoing Thermal Relaxation

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