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Meeting MS&T22: Materials Science & Technology
Symposium Glasses and Optical Materials: Current Issues and Functional Applications
Presentation Title Effect of Ion-exchange Strengthening on the Mechanical Behavior of Sodium Aluminophosphosilicate Glass
Author(s) Kasimuthumaniyan S, Allu Amarnath Reddy, N. M. Anoop Krishnan, Nitya Nand Gosvami
On-Site Speaker (Planned) N. M. Anoop Krishnan
Abstract Scope The brittleness of glasses restricts their application in structural and load-bearing components. Ion-exchange strengthening is a well-known method for reducing their brittleness by delaying the crack propagation. Herein, we investigate the role of the ion-exchange duration on the mechanical behavior of glasses. The sodium aluminophosphosilicate glass is subjected to ion-exchange in a KNO3 salt bath for varied durations. We employ Vickers micro-indentation to mimic the sharp contact loading on the glass surface and note a significant suppression of the strength-reducing radial-median cracks post ion-exchange. The ion-exchanged glasses exhibit crack resistance (CR) up to 150 N against the 11.2 N CR value for non ion-exchanged glass. Further, we also report the ion-exchange duration-dependent elastoplastic behavior of glasses via nanoindentation. Finally, we compare the scratch behavior of the ion-exchanged glasses with the non ion-exchanged glass. Altogether, this work explores the micro and nanomechanical response of ion-exchanged glasses to normal and lateral loading.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

3D Mapping of Glass Indentation Stress Fields
Continuation of the Investigation of Double Ion-exchange in Mixed Alkali-lime Silicate Glasses
D-13: Flow Dissolution of Lithium Disilicate Glass under Aqueous Conditions
D-15: Natural Glasses – Findings from an Undergraduate Project
D-17: Sulfur Blue Glasses - S3- Anion Charge Transfer Transitions
D-18: Tungsten Borate – A Replacement for Lead in Glass
D-19: Unusual High Oxidation States of Transition Metal Ions in Silicate Glasses of High Optical Basicity: Trivalent Co3+ and Ni3+
Effect of Ion-exchange Strengthening on the Mechanical Behavior of Sodium Aluminophosphosilicate Glass
Effect of Modifier Cation Type on Structure and Nickel Speciation in Alkali Borosilicate Glasses
Glass Structure-Terahertz Properties Relationship: Power-Law Model and Deviations in Sodium Borosilicate, Tellurite, and Chalcogenide Glass Families
Intermediate-range Order in Organic Glasses
Ionic Glasses: An Emerging Separate Class of Amorphous Materials with Unique Topology and Dynamic Properties
Lithium-iron Silicate Glasses as Simulations of High-Fe Nuclear Waste Glass
MD Simulations of SLS Batch Melting
Multispectroscopic Study of Lead Borate Glasses
Oxygen Triclusters and Five-Coordinated Alumina Species in Calcium-aluminosilicate Glasses
Structural Relaxation Mechanism of Anisotropic Alkali Metaphosphate Glass
Structure-property Relationship in Mixed Oxy-sulfide Glassy Solid Electrolyte Material: 0.58Li2S + 0.42 [(1–y­)SiS2 + yLiPO3]
The Dissolution of Lithium Disilicate Glass under Ultrasonic Cavitation
The Problem with Lead
Uncovering Hidden Glasses
Utilizing Electrical Impedance Spectroscopy (E.I.S.) to Observe In-situ Phase Changes in Lithium Diborate Glass Undergoing Thermal Relaxation

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