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Meeting MS&T21: Materials Science & Technology
Symposium Preceramic Polymers; Synthesis, Processing, Modeling, and Derived Ceramics
Presentation Title X-ray Computed Tomography Investigation of CMC Densification via Polymer Infiltration and Pyrolysis
Author(s) Derek S. King, Thomas Key, Connor Wycoff, Craig Przybyla, Michael Cinibulk
On-Site Speaker (Planned) Derek S. King
Abstract Scope X-ray computed tomography (XCT) was utilized to analyze a plain weave, carbon fiber, ceramic matrix composite (CMC) and assess its densification via the polymer infiltration and pyrolysis (PIP) process. The relative nesting and stacking of tows in the X and Y directions, for adjacent plies, produced three ply relationships, defined as Type I, Type II, and Type III. These ply relationships were correlated to the formation of large void spaces within the composite. Such void spaces have been previously observed to remain, even after PIP densification. XCT analysis after each PIP cycle revealed that fine void features, such as cracks or delaminations, were filled and began to densify from the first PIP cycle; however, the large void structure remained unfilled. In this talk, the formation of the large void structure will be discussed and the possible mechanisms that prohibit or facilitate CMC densification, via PIP processing, will be introduced.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Additive Manufacturing of Hybrid Polymer-derived Ceramics via Core-shell Direct-ink Writing
Atomistic Simulations of Polymer Pyrolysis
Effect of Pendant Groups on the Mass Yield, Density and Process Modeling of Polycarbosilanes during Pyrolysis
Embedded Direct Ink Writing of Freeform Ceramic Components
Evolutive State and Damage Modeling and Characterization for PIP-based Hypersonic Vehicle Materials
Fabrication of SiOC Fibermats via Electrospinning and their Applications in Energy Storage Systems
Impact of Preceramic Polymer Architecture on Derived Ceramics
Investigation of Polymer Derived SiOC/Carbon Nanotube Electrodes for Na-ion Batteries
Isoconversional Methods and Kinetic Reaction Models for Cure Modelling of Commercial Pre-ceramic Polymers and their Blends
Laser and Furnace Pyrolyzed Organosilazane-based Glass/ZrO2 Composite Coating Systems: A Comparison
Metal-coordinated Preceramic Polymer Hairy Nanoparticles for Ultra-high Temperature Structural Materials
Molecules, Polymers, and Rings: Preceramic Compounds for AsB Formation
Novel Hydrogen Chemisorption Properties of Polymer-derived Amorphous SiAlN Compounds
Organics Matter: Common Features in Energetics of Polymer Derived Ceramics, Metal Organic Frameworks, and other Hybrid Materials
Polymer-derived UHTC Synthesis
Porous SiOC/SiC Ceramics via an Active-filler Catalyzed Polymer-derived Method
Preceramic Polymer Organization via Block Copolymer Templating
Preparation of ZrC-embedded Glass-like Carbon Wires via Thermal Decomposition of Metal Organic Frameworks
SiOC Coatings on Yttria Stabilized Zirconia Microspheres Using a Fluidized Bed Coating Process
Study on Manufacturing of Silsesquiazane Derived Hierarchically Porous Silicon Carbonitride Ceramics with Aligned Macropore by Freeze-casting Method
Superparamagnetic Silicon Carbonitride Ceramic Fibers through In-situ Generation of Iron Silicide Nanoparticles
Synthesis and 3D Printing of Antibacterial Polymer-derived Bioceramic Scaffolds for Bone Engineering Applications
Synthesis of Precursor Derived Si(B)CN Ceramic Coating for High-temperature Applications
Thermal and Rheological Properties of Preceramic Polymer Grafted Nanoparticles
Thermomechanical Performance of a Novel Class of Ultra-high Temperature Polymer Derived La Containing Zr-B-C-(O) Ceramics
UV Curable Preceramic Polymers and their Application in Additive Manufacturing
X-ray Computed Tomography Investigation of CMC Densification via Polymer Infiltration and Pyrolysis

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