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Meeting MS&T21: Materials Science & Technology
Symposium Preceramic Polymers; Synthesis, Processing, Modeling, and Derived Ceramics
Presentation Title Additive Manufacturing of Hybrid Polymer-derived Ceramics via Core-shell Direct-ink Writing
Author(s) Robert Cody Pack, James Willie Kemp, Brett G. Compton
On-Site Speaker (Planned) Robert Cody Pack
Abstract Scope A significant amount of work in recent years has focused on the use of preceramic polymer feedstocks filled with structural and/or functional fillers such as carbides, nitrides, and other carbon fillers. Such work provides a foundation and opportunity for new material formulation and additive manufacturing (AM) process development that we aim to build upon. In this work, we utilize the AM process of direct-ink writing, coupled with implementation of a novel co-extrusion, core-shell printhead, to fabricate hybrid polymer-derived ceramic composites with a core-shell motif to achieve unique structural and functional properties. Specifically, this talk will focus on the creation and characterization of electrically conductive and insulating polysilazane-derived materials to enable AM of high temperature sensors and related applications. Rheological characterization, printing behavior, and post-pyrolysis properties will be highlighted, and challenges with co-processing in the core-shell motif will be discussed.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Additive Manufacturing of Hybrid Polymer-derived Ceramics via Core-shell Direct-ink Writing
Atomistic Simulations of Polymer Pyrolysis
Effect of Pendant Groups on the Mass Yield, Density and Process Modeling of Polycarbosilanes during Pyrolysis
Embedded Direct Ink Writing of Freeform Ceramic Components
Evolutive State and Damage Modeling and Characterization for PIP-based Hypersonic Vehicle Materials
Fabrication of SiOC Fibermats via Electrospinning and their Applications in Energy Storage Systems
Impact of Preceramic Polymer Architecture on Derived Ceramics
Investigation of Polymer Derived SiOC/Carbon Nanotube Electrodes for Na-ion Batteries
Isoconversional Methods and Kinetic Reaction Models for Cure Modelling of Commercial Pre-ceramic Polymers and their Blends
Laser and Furnace Pyrolyzed Organosilazane-based Glass/ZrO2 Composite Coating Systems: A Comparison
Metal-coordinated Preceramic Polymer Hairy Nanoparticles for Ultra-high Temperature Structural Materials
Molecules, Polymers, and Rings: Preceramic Compounds for AsB Formation
Novel Hydrogen Chemisorption Properties of Polymer-derived Amorphous SiAlN Compounds
Organics Matter: Common Features in Energetics of Polymer Derived Ceramics, Metal Organic Frameworks, and other Hybrid Materials
Polymer-derived UHTC Synthesis
Porous SiOC/SiC Ceramics via an Active-filler Catalyzed Polymer-derived Method
Preceramic Polymer Organization via Block Copolymer Templating
Preparation of ZrC-embedded Glass-like Carbon Wires via Thermal Decomposition of Metal Organic Frameworks
SiOC Coatings on Yttria Stabilized Zirconia Microspheres Using a Fluidized Bed Coating Process
Study on Manufacturing of Silsesquiazane Derived Hierarchically Porous Silicon Carbonitride Ceramics with Aligned Macropore by Freeze-casting Method
Superparamagnetic Silicon Carbonitride Ceramic Fibers through In-situ Generation of Iron Silicide Nanoparticles
Synthesis and 3D Printing of Antibacterial Polymer-derived Bioceramic Scaffolds for Bone Engineering Applications
Synthesis of Precursor Derived Si(B)CN Ceramic Coating for High-temperature Applications
Thermal and Rheological Properties of Preceramic Polymer Grafted Nanoparticles
Thermomechanical Performance of a Novel Class of Ultra-high Temperature Polymer Derived La Containing Zr-B-C-(O) Ceramics
UV Curable Preceramic Polymers and their Application in Additive Manufacturing
X-ray Computed Tomography Investigation of CMC Densification via Polymer Infiltration and Pyrolysis

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