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Meeting MS&T21: Materials Science & Technology
Symposium Preceramic Polymers; Synthesis, Processing, Modeling, and Derived Ceramics
Presentation Title Evolutive State and Damage Modeling and Characterization for PIP-based Hypersonic Vehicle Materials
Author(s) Rick Hall, Zlatomir Apostolov, Ashley Hilmas, George Jefferson, Vikas Varshney, Michael Cinibulk, Robert Brockman, Rebecca Hoffman, Thomas Key, Derek King
On-Site Speaker (Planned) Rick Hall
Abstract Scope While it allows for scale, relative expediency, and extreme durability, the unpredictable nature of microstructural evolution during PIP processing in the form of cracks, pores, and strain rates leads to significant variability in final CMC properties and shape. This is currently the most significant obstacle towards broader CMC utilization. The proposed work will develop material models driven by detailed experimental observations to better understand the variability in microstructural evolution during PIP processing, and the consequent effects on the composite’s ability to function as intended in hypersonic environments. The modeling aspect of this work will feature the precursor chemomechanical evolution during infiltration, cure, and pyrolysis of C/SiC, along with C/SiC oxidation behavior under representative in-service environments. A continuum/discrete damage and porosity simulation framework is being developed, which is capable of rendering the coupling between pyrolytic, oxidative, large volumetric, thermal and viscous responses of the constituent materials during multiple PIP processing cycles.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Additive Manufacturing of Hybrid Polymer-derived Ceramics via Core-shell Direct-ink Writing
Atomistic Simulations of Polymer Pyrolysis
Effect of Pendant Groups on the Mass Yield, Density and Process Modeling of Polycarbosilanes during Pyrolysis
Embedded Direct Ink Writing of Freeform Ceramic Components
Evolutive State and Damage Modeling and Characterization for PIP-based Hypersonic Vehicle Materials
Fabrication of SiOC Fibermats via Electrospinning and their Applications in Energy Storage Systems
Impact of Preceramic Polymer Architecture on Derived Ceramics
Investigation of Polymer Derived SiOC/Carbon Nanotube Electrodes for Na-ion Batteries
Isoconversional Methods and Kinetic Reaction Models for Cure Modelling of Commercial Pre-ceramic Polymers and their Blends
Laser and Furnace Pyrolyzed Organosilazane-based Glass/ZrO2 Composite Coating Systems: A Comparison
Metal-coordinated Preceramic Polymer Hairy Nanoparticles for Ultra-high Temperature Structural Materials
Molecules, Polymers, and Rings: Preceramic Compounds for AsB Formation
Novel Hydrogen Chemisorption Properties of Polymer-derived Amorphous SiAlN Compounds
Organics Matter: Common Features in Energetics of Polymer Derived Ceramics, Metal Organic Frameworks, and other Hybrid Materials
Polymer-derived UHTC Synthesis
Porous SiOC/SiC Ceramics via an Active-filler Catalyzed Polymer-derived Method
Preceramic Polymer Organization via Block Copolymer Templating
Preparation of ZrC-embedded Glass-like Carbon Wires via Thermal Decomposition of Metal Organic Frameworks
SiOC Coatings on Yttria Stabilized Zirconia Microspheres Using a Fluidized Bed Coating Process
Study on Manufacturing of Silsesquiazane Derived Hierarchically Porous Silicon Carbonitride Ceramics with Aligned Macropore by Freeze-casting Method
Superparamagnetic Silicon Carbonitride Ceramic Fibers through In-situ Generation of Iron Silicide Nanoparticles
Synthesis and 3D Printing of Antibacterial Polymer-derived Bioceramic Scaffolds for Bone Engineering Applications
Synthesis of Precursor Derived Si(B)CN Ceramic Coating for High-temperature Applications
Thermal and Rheological Properties of Preceramic Polymer Grafted Nanoparticles
Thermomechanical Performance of a Novel Class of Ultra-high Temperature Polymer Derived La Containing Zr-B-C-(O) Ceramics
UV Curable Preceramic Polymers and their Application in Additive Manufacturing
X-ray Computed Tomography Investigation of CMC Densification via Polymer Infiltration and Pyrolysis

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