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Meeting 2023 TMS Annual Meeting & Exhibition
Symposium High Temperature Electrochemistry V
Presentation Title The Demonstration and Optimization of Thin-cell Electrochemical Measurements in Molten LiCl-KCl Eutectic
Author(s) Cameron Vann, Tyler Williams, Devin Rappleye
On-Site Speaker (Planned) Cameron Vann
Abstract Scope While solvation limits low temperature electrochemistry to primarily dilute samples, molten salt electrochemistry has no such limitations. For processes such as monitoring an electrorefiner or molten salt reactor, sensors that operate in highly concentrated regimes need to be developed. To this end, thin-cell apparatuses and techniques have been developed for use in molten salts. These thin-cell sensors can make concentration measurements of dilute and concentrated samples with short measurement times. Even chronocoulometric measurements have low latency because thin-cells isolate a few µL from the solution for analysis. The accuracy of these sensors has been tested in concentrations from 1 to 50 wt%.
Proceedings Inclusion? Planned:
Keywords Other, Other, Other

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Revised High Temperature Synthesis of UCl3 via Reaction of U with FeCl2
Blind Identification and Quantification of Analytes in Molten LiCl-KCl Eutectic
Chloro-aluminate Species Distribution Correlation with Electrical Conductivity of 1-ethyl-3-methyl Imidazolium Chloride (EMIC)-Aluminum Chloride (AlCl3) System
Cyclic Voltammetry for Real-time Oxide Ion Concentration Measurements of a Molten CaCl2
Electrochemical Behavior of Bismuth in molten LiCl-KCl-CaCl2
Electrochemical Properties of Ca-Sb Metal Battery with a Molten Chloride Electrolyte
Electrochemical Reduction of Nd2O3+Fe2O3 Mixed Oxide Precursors in Calcium Chloride Melt
Evaluating the Effects of Mixed Cation Molten Salt Electrolytes within the Li-Sb-Sn Liquid Metal Battery System
Evaluating the Electrochemical Recovery of Gd Using a Reactive Liquid Bi Electrode
Formation of Carbon Layer on Ni and Mo Through Electrochemical Reduction of Carbonate Ions in Molten LiCl
Numerical Modelling and Phase Field Modelling of Silicon Electrodeposition for Solar Cells at High Temperatures using Molten Salts
On the Separation of Niobium and Tantalum Metals via Molten Sulfide Electrolysis
Optimisation of the Anodic and Cathodic Current Densities during Nd Electrowinning Process
Oxide Ion Ceramic Sensor in Molten CaCl2 for Real Time Monitoring of the Direct Oxide Reduction Process
Relative Performance of Platinum, Iridium, and Ruthenium as Oxygen-Evolving Anodes during the Electrolytic Reduction of Uranium Oxide in Molten LiCl-Li2O
Study of Potentiometry for Monitoring Activity of GdCl3 in Molten LiCl-KCl Salt
The Demonstration and Optimization of Thin-cell Electrochemical Measurements in Molten LiCl-KCl Eutectic
The Impact of Moisture on the Electrochemical Behavior of Molten Calcium Chloride
Thermodynamic Properties of Nd-Fe Alloys via EMF Measurements in Molten Salts

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