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Meeting 2023 TMS Annual Meeting & Exhibition
Symposium High Temperature Electrochemistry V
Presentation Title Blind Identification and Quantification of Analytes in Molten LiCl-KCl Eutectic
Author(s) Tyler Williams, Greg Chipman, Ranon Fuller, Mark Schvaneveldt, Jason Torrie, Devin Rappleye
On-Site Speaker (Planned) Tyler Williams
Abstract Scope Electroanalytical techniques are promising tools for process monitoring and material accountancy in molten salt processes. However, most published studies demonstrating their potential begin with some process knowledge of the compounds present and the range of concentrations expected. This study tests the ability of electroanalytical measurements to identify unknown species and quantify their concentrations in molten LiCl-KCl eutectic by performing blind measurements and analysis on mixtures prepared by someone other than the operator performing the measurement. The operator will use the published literature and their knowledge of electrochemical methods to identify and quantify the analyte(s) present. The results of each blind measurement and analysis will be presented.
Proceedings Inclusion? Planned:
Keywords Electrometallurgy, Pyrometallurgy, Characterization

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Revised High Temperature Synthesis of UCl3 via Reaction of U with FeCl2
Blind Identification and Quantification of Analytes in Molten LiCl-KCl Eutectic
Chloro-aluminate Species Distribution Correlation with Electrical Conductivity of 1-ethyl-3-methyl Imidazolium Chloride (EMIC)-Aluminum Chloride (AlCl3) System
Cyclic Voltammetry for Real-time Oxide Ion Concentration Measurements of a Molten CaCl2
Electrochemical Behavior of Bismuth in molten LiCl-KCl-CaCl2
Electrochemical Properties of Ca-Sb Metal Battery with a Molten Chloride Electrolyte
Electrochemical Reduction of Nd2O3+Fe2O3 Mixed Oxide Precursors in Calcium Chloride Melt
Evaluating the Effects of Mixed Cation Molten Salt Electrolytes within the Li-Sb-Sn Liquid Metal Battery System
Evaluating the Electrochemical Recovery of Gd Using a Reactive Liquid Bi Electrode
Formation of Carbon Layer on Ni and Mo Through Electrochemical Reduction of Carbonate Ions in Molten LiCl
Numerical Modelling and Phase Field Modelling of Silicon Electrodeposition for Solar Cells at High Temperatures using Molten Salts
On the Separation of Niobium and Tantalum Metals via Molten Sulfide Electrolysis
Optimisation of the Anodic and Cathodic Current Densities during Nd Electrowinning Process
Oxide Ion Ceramic Sensor in Molten CaCl2 for Real Time Monitoring of the Direct Oxide Reduction Process
Relative Performance of Platinum, Iridium, and Ruthenium as Oxygen-Evolving Anodes during the Electrolytic Reduction of Uranium Oxide in Molten LiCl-Li2O
Study of Potentiometry for Monitoring Activity of GdCl3 in Molten LiCl-KCl Salt
The Demonstration and Optimization of Thin-cell Electrochemical Measurements in Molten LiCl-KCl Eutectic
The Impact of Moisture on the Electrochemical Behavior of Molten Calcium Chloride
Thermodynamic Properties of Nd-Fe Alloys via EMF Measurements in Molten Salts

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