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Meeting 2022 TMS Annual Meeting & Exhibition
Symposium 2022 Technical Division Student Poster Contest
Presentation Title SPG-35: Discovering the Corrosion Mechanism of Chromium in High-temperature LiF-NaF-KF Molten Salts for Gen-IV Molten Salt Reactor Applications
Author(s) Ho Lun Chan, Elena Romanovskaia, Minsung Hong, Peter Hosemann, John Scully
On-Site Speaker (Planned) Ho Lun Chan
Abstract Scope Chromium, a ubiquitous and powerful alloying element possible structural materials in advanced nuclear reactor alloys, is susceptible to selective dissolution in molten fluoride salts in the presence of hydrofluoric acid, which is formed by the adsorption and reaction of moisture impurity in molten fluorides. In this project, the thermodynamic stability of Cr in the Cr0, Cr2+ and Cr3+ oxidation states considering various F- ion coordination was investigated in molten LiF-NaF-KF (FLiNaK) eutectic salt. Corrosion was a strong function of thermodynamic and kinetic factors. Potential-fluoride ion activity diagrams were constructed to predict the F- stability region where spontaneous corrosion of Cr occurs. Electrochemical methods were utilized to relate the interface corrosion kinetics to the predicted stability region. The present work aims to identify key thermodynamic and kinetic factors that are significant to the chromium corrosion for molten salt nuclear reactor applications.
Proceedings Inclusion? Undecided
Keywords High-Temperature Materials, Nuclear Materials, Other

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

SPG-10: Assessing the Bio-stability of miRNA Conjugated Metal and Metal Oxide Nanoparticles via Electroanalysis
SPG-11: Crumpled MoS2 Flexoelectric Energy Harvester
SPG-12: Dual miRNAs Functionalized Cerium Oxide for Angiogenesis and Anti-inflammatory
SPG-13: Engineering Ce3+ State in Cerium Oxide Nanoparticles Under The Presence of a Reducing Sugar
SPG-16: Study of Anti-inflammatory miRNA146a Loading on Cerium Oxide Nanoparticles with Different Surface Facet
SPG-17: Upconversion Nanomaterials (UCNPs) Based Self-sterilizing Surfaces with Efficacy Against SARS-CoV-2
SPG-18: A Promising Orthopedic Implant Material with Enhanced Corrosion Resistance, Mechanical Properties, Osteogenic and Antibacterial Activity: Mg-Sc-Sr Alloy
SPG-19: Development of Equiaxed Titanium Alloys in Additive Manufacturing
SPG-1: Challenges for Molten Oxide Electrolysis in Reduced Gravity
SPG-20: Effects of Cu on the Interfacial Stability of Nanoprecipitates in Al-Zn-Mg-Cu Alloys from First-principles Investigations
SPG-22: Microstructural Evolution during Post Processing of Additively Manufactured 7050 Aluminum Alloy and Its Effect on Corrosion Behavior
SPG-23: Prior Grain Boundary Alpha in BASCA Ti-17
SPG-28: Microstructure and Mechanical Properties of Eutectic Ni-Ce and Ni-Ce-Al Alloys
SPG-29: Production via Machining and Rolling of High Resistivity Electrical Steel
SPG-2: Decopperization Study for Steel Recycling
SPG-32: Water Transport through Porous Membranes - Modeling and Experiments
SPG-33: Computational Modeling of Non-equilibrium Phenomena in Laser Additive Manufacturing Using Molecular Dynamics
SPG-34: Development of a Generalized Fatigue Assessment Approach for Steel Castings
SPG-35: Discovering the Corrosion Mechanism of Chromium in High-temperature LiF-NaF-KF Molten Salts for Gen-IV Molten Salt Reactor Applications
SPG-36: Effect of Oxide Impurities on Corrosion of Materials in Molten Fluoride Salt
SPG-39: Mechanical Behavior of a Next-generation Steel (AF9628) Printed via Directed Energy Deposition
SPG-3: Influence of Graphene Nano Sheets on Friction and Wear Behaviour of Aluminum A380 Nanocomposite Produced by Powder Metallurgy
SPG-4: Investigating of the Microstructure and Mechanical Properties of Al- A380 Nanocomposite Reinforced with SiC Nanoparticles Produced by Powder Metallurgy
SPG-5: Investigating of the Wear Behavior of Al- A380 Nanocomposite Reinforced with SiC Nanoparticles Produced by Powder Metallurgy
SPG-6: Recycling of CrC-nichrome Coated Stainless Steel by Remelting and Addition of Alloys with Validation from Mathematical Modelling
SPG-7: Sustainable Process Flowsheet for Recovery of Value added Products from Bauxite Residue
SPG-8: The Effect of Graphene Nano Sheets on Microstructure and Mechanical Properties of Aluminum A380 Nanocomposite Produced by Powder Metallurgy
SPU-10: Correlating Grain Boundary Energy to Abnormal Grain Growth Using Atomic Force Microscopy
SPU-11: Model Based Control of Microstructure for Additive Manufacturing 316L Stainless Steel
SPU-12: Quantitative Analysis of Microstructure in the Ti-6Al-4V Alloy Using Scanning Electron Microscopy
SPU-2: Small bugs for big problems: Enriching microbes to degrade plastics
SPU-3: Investigation of Nanoparticle Size Effects on the Dielectric Properties of Functionalized Barium Titanate
SPU-4: Medical Applications of Polymer Coated Cannulas
SPU-5: Thermomechanical Clamp for Curing Low-κ Dielectric Dry Films
SPU-7: Investigate the Effect of Crystallographic Orientation on the Mechanical and Corrosion Properties of Copper Single Crystals
SPU-8: COMSOL-generated Weld Heat Transfer Models For Automation of Infrared Thermography Non-destructive Testing (IR-TNDT) Image Analysis
SPU-9:Mechanochemistry for Creation of Functional Surface Treatments

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