About this Abstract | 
  
   
    | Meeting | 
    2024 TMS Annual Meeting & Exhibition
       | 
  
   
    | Symposium 
       | 
    Bio-Nano Interfaces and Engineering Applications
       | 
  
   
    | Presentation Title | 
    Interpenetrating Polymer Network as Interface Material in Bioinspired Composites | 
  
   
    | Author(s) | 
    Hortense  Le Ferrand | 
  
   
    | On-Site Speaker (Planned) | 
    Hortense  Le Ferrand | 
  
   
    | Abstract Scope | 
    
Natural ceramic composites are notable for their outstanding mechanical properties that results from their complex microstructure and the presence of weak interfaces from a low strength organic glue between the mineral particles. 
Using aluminum oxide platelets as the mineral reinforcement, we create hierarchical composites with well-define microstructure and a bio-mimicking organic interface. We simultaneously assemble the platelets into their microstructure and crosslink the surrounding matrix in a one-pot synthesis method. The microstructure is obtained using magnetically assisted slip casting while the matrix is an interpenetrated polymer network (IPN) made of polyacrylamide and polyN-isopropylacrylamide. Coupled with an alternating microstructure, the IPN interface enhances the compressive toughness of the composites by 205 % as compared to the the composites with horizontal or vertical microstructure, with less than 35% reduction on the stiffness. This approach opens the opportunity to study the influence of water as a plasticizer and to include chemical grafting. | 
  
   
    | Proceedings Inclusion? | 
    Planned:  | 
  
 
    | Keywords | 
    Composites, Surface Modification and Coatings,  |