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Meeting Materials Science & Technology 2020
Symposium Synthesis, Characterization, Modeling and Applications of Functional Porous Materials
Presentation Title Experimental Thermodynamics of Zeolites and Metal-organic Frameworks
Author(s) Xianghui Zhang, Cody Cockreham, Esra Yılmaz, Baodong Wang, Hui Sun, Di Wu
On-Site Speaker (Planned) Di Wu
Abstract Scope The development, characterization and applications of porous materials are critical for sustainable conversion and separation of petrochemical compounds, carbon capture and sequestration. Here, I introduce our recent experimental thermodynamic (calorimetric) studies on the synthesis, application and decomposition of two families of porous materials, zeolites and metal-organic frameworks (MOFs), including in situ synthesis of spherical zeolite A and X pellets, energetics of transition metal ion-exchanged zeolites (mordenite, ZSM-5 and SSZ-13), thermal decomposition of bimetallic MOF-74 and the applications of zeolites and MOFs in hydrocarbon separation. The results highlight the crucial role of thermodynamic factors, which govern the material stability and guest – host interactions.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

An Overview of High-temperature Ceramic-carbonate Dual-phase Membranes for CO2 Capture and Conversion
Compositional Influence on Kirkendall Pore Formation during Fabrication of Gamma Prime Strengthened Superalloy Microtubes
Crystallinity Effect on Mesoporous TiO2 Nanoparticle Negative Electrode Material for Metal Ion Batteries
Density Functional Theory Study of the Porous Metal-organic Framework Material Ni-Bpy-Me
Designing Multi-phase Reaction Pathways for CO2 Capture and Enhanced H2 Production from Ca- and Mg-bearing Precursors to Produce Stable Porous Carbonates Using Cross-scale X-ray Scattering Measurements
Development of Nanostructured Vycor Glass Microspheres for Doxorubicin Administration
Experimental Thermodynamics of Zeolites and Metal-organic Frameworks
Hierarchical Porosity in δ-MnO2 Nanosheet Assemblies via Layer-tunnel Conversion
Highly Controlled and Steerable Porosity for Ceramic Structures via Freeze Casting
Introductory Comments: Synthesis, Characterization, Modeling and Applications of Functional Porous Materials
Low/Intermediate Temperature Polysiloxane Derived Ceramics with Increased Carbon for Electrical Applications
Luminescent Metal-organic Framework-Based Sensors of Rare Earth Elements in Aqueous Streams
Porous Crystalline Porphyrinic Structures for Functional Materials Applications
Porous Organic Cage Composite Membranes for Post-combustion CO2 Separation
Surface Modified ScSZ-MC Dual-phase Membrane for Pre-combustion CO2 Capture
Synchrotron Structure and Sorption Properties of a Metal Organic Framework Compound Ni(3-methyl-4,4’-bipyridine)[Ni(CN)4] for CO2 Mitigation Application
The Influence of Yttria Content and Synthetic Parameters on the Thermal Stability of Yttria-stabilized Zirconia Aerogels
Thermodynamics of Naturally Occurring 2D and 3D Mineral Hosts: Zeolites, Layered Double Hydroxides and Clays

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