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Meeting Materials Science & Technology 2020
Symposium Synthesis, Characterization, Modeling and Applications of Functional Porous Materials
Presentation Title Compositional Influence on Kirkendall Pore Formation during Fabrication of Gamma Prime Strengthened Superalloy Microtubes
Author(s) Haozhi Zhang, Ashley Paz y Puente
On-Site Speaker (Planned) Haozhi Zhang
Abstract Scope Hollow superalloys provide several advantages, but are difficult to fabricate, particularly on the micro-scale. The Kirkendall effect offers a novel route to produce such hollowed micro-objects using an inside-out diffusion approach instead of traditional template-removal methods. By depositing the desired alloying additions on Ni-based wires via a chemical vapor deposition technique called pack cementation, multi-component microtubes can be fabricated by taking advantage of the radial symmetry and spatial confinement present within the structure, which under the appropriate annealing conditions, leads to the formation of a central, continuous Kirkendall channel internally throughout the wire, converting it into a microtube. The influence of various alloying additions and processing conditions on the Kirkendall pore formation and evolution will be discussed here. Finally, de-alloying via reversing the pack cementation process was used in an attempt to tailor the composition to achieve the precipitation strengthened γ/γ’ microstructure and the desired hollow geometry simultaneously.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

An Overview of High-temperature Ceramic-carbonate Dual-phase Membranes for CO2 Capture and Conversion
Compositional Influence on Kirkendall Pore Formation during Fabrication of Gamma Prime Strengthened Superalloy Microtubes
Crystallinity Effect on Mesoporous TiO2 Nanoparticle Negative Electrode Material for Metal Ion Batteries
Density Functional Theory Study of the Porous Metal-organic Framework Material Ni-Bpy-Me
Designing Multi-phase Reaction Pathways for CO2 Capture and Enhanced H2 Production from Ca- and Mg-bearing Precursors to Produce Stable Porous Carbonates Using Cross-scale X-ray Scattering Measurements
Development of Nanostructured Vycor Glass Microspheres for Doxorubicin Administration
Experimental Thermodynamics of Zeolites and Metal-organic Frameworks
Hierarchical Porosity in δ-MnO2 Nanosheet Assemblies via Layer-tunnel Conversion
Highly Controlled and Steerable Porosity for Ceramic Structures via Freeze Casting
Introductory Comments: Synthesis, Characterization, Modeling and Applications of Functional Porous Materials
Low/Intermediate Temperature Polysiloxane Derived Ceramics with Increased Carbon for Electrical Applications
Luminescent Metal-organic Framework-Based Sensors of Rare Earth Elements in Aqueous Streams
Porous Crystalline Porphyrinic Structures for Functional Materials Applications
Porous Organic Cage Composite Membranes for Post-combustion CO2 Separation
Surface Modified ScSZ-MC Dual-phase Membrane for Pre-combustion CO2 Capture
Synchrotron Structure and Sorption Properties of a Metal Organic Framework Compound Ni(3-methyl-4,4’-bipyridine)[Ni(CN)4] for CO2 Mitigation Application
The Influence of Yttria Content and Synthetic Parameters on the Thermal Stability of Yttria-stabilized Zirconia Aerogels
Thermodynamics of Naturally Occurring 2D and 3D Mineral Hosts: Zeolites, Layered Double Hydroxides and Clays

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