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Meeting MS&T21: Materials Science & Technology
Symposium Functional Defects in Electroceramic Materials
Presentation Title Ceramics Are Brittle. Can Dislocations Change That?
Author(s) Lukas Porz, Arne Klomp, Xufei Fang, Ning Li, Can Yildirim, Carsten Detlefs, Enrico Bruder, Marion Höfling, Wolfgang Rheinheimer, Eric Patterson, Peng Gao, Karsten Durst, Atsutomo Nakamura, Karsten Albe, Hugh Simons, Jürgen Rödel
On-Site Speaker (Planned) Lukas Porz
Abstract Scope While the effect of dislocations on functional properties is increasingly appreciated, dislocations have barely been considered for toughening ceramics. Despite outstanding deformability of a range of ceramic single crystals (e.g., LiF, MgO or SrTiO3) at room temperature, an effect of dislocations on fracture toughness was rarely observed. Why? Here, we show that introducing a high dislocation density can allow local plasticity which is key for desirable mechanical properties. With local deformation enabled, stress concentrations around flaws or indents can be mitigated by plastic flow. In effect, crack nucleation and propagation are substantially reduced [1]. In consequence, dislocations can be a new avenue to combat short cracks and increase device reliability. Conventionally sintered samples, however, are not suitable as this process renders ceramics dislocation-free.1)Porz et al., Materials Horizons, 2021 (DOI:10.1039/d0mh02033h)

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Accelerated Synthesis and In-situ X-ray Pair Distribution Functions of Substituted Vanadium Dioxide
Ceramics Are Brittle. Can Dislocations Change That?
Defect-promoted Sulfur Cathode for Highly Stable Sodium-sulfur Batteries
Dislocation-based Nanomechanics in Functional Oxides: A Case Study on SrTiO3
Dislocations as “Self-dopants” in Functional Oxides, Exemplified for TiO2
Irradiation-enhanced Electrochemical Performance of TiO2 Anode Material
Let Thermodynamics do Interfacial Engineering
Leveraging Structure and Energetics to Enhance Electrochemical Kinetics in Batteries
Modeling the Electrical Double Layer at Solid-state Electrochemical Interfaces
Now On-Demand Only - Understanding Lithium Plating in Graphite and Silicon for Fast Charging Li-ion Battery

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