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Meeting MS&T21: Materials Science & Technology
Symposium Functional Defects in Electroceramic Materials
Presentation Title Dislocation-based Nanomechanics in Functional Oxides: A Case Study on SrTiO3
Author(s) Xufei Fang, Kuan Ding, Stephan Janocha, Christian Minnert, Till Frömling, Karsten Durst, Atsutomo Nakamura, Jürgen Rödel
On-Site Speaker (Planned) Xufei Fang
Abstract Scope In light of the rising topic of dislocation-based functionality of oxides, the dislocation-based mechanical behavior, for instance, dislocation plasticity and potentially crack formation induced by dislocations is also drawing increasing attention. Understanding the dislocation-based mechanics in oxides can play a critical role in assessing the materials’ mechanical and functional reliability. Here we present an approach to actively engineer and evaluate the incipient dislocation plasticity and crack formation using nanoindentation. We propose the concept of “defect chemistry engineering” to actively tune the dislocation plasticity of the oxide crystals, as will be demonstrated in single-crystal SrTiO3. Two methods, i.e., via stoichiometry change of the Sr/Ti ratio, and by reduction treatment to increase oxygen vacancy concentration, have been validated to modify the dislocation nucleation and motion. Our approach may also serve as a potential method to increase the fracture toughness of the material with appreciable dislocation plasticity achieved.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Accelerated Synthesis and In-situ X-ray Pair Distribution Functions of Substituted Vanadium Dioxide
Ceramics Are Brittle. Can Dislocations Change That?
Defect-promoted Sulfur Cathode for Highly Stable Sodium-sulfur Batteries
Dislocation-based Nanomechanics in Functional Oxides: A Case Study on SrTiO3
Dislocations as “Self-dopants” in Functional Oxides, Exemplified for TiO2
Irradiation-enhanced Electrochemical Performance of TiO2 Anode Material
Let Thermodynamics do Interfacial Engineering
Leveraging Structure and Energetics to Enhance Electrochemical Kinetics in Batteries
Modeling the Electrical Double Layer at Solid-state Electrochemical Interfaces
Now On-Demand Only - Understanding Lithium Plating in Graphite and Silicon for Fast Charging Li-ion Battery

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