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Meeting 2024 TMS Annual Meeting & Exhibition
Symposium High Temperature Electrochemistry: An FMD Symposium Honoring Uday B. Pal
Presentation Title Mitigating Fuel Electrode Degradation in SOECs by Infiltrated of Nanoscale GDC Catalyst
Author(s) Emily Ghosh, John-In Lee, Jillian R. Mulligan, Uday B. Pal, Srikanth Gopalan, Soumendra N. Basu
On-Site Speaker (Planned) Emily Ghosh
Abstract Scope Hydrogen storage has become important in meeting future energy demands using renewable and clean energy technologies. Solid oxide electrolysis cells (SOECs) provide a promising option for hydrogen production and energy storage with high efficiency. While many advancements have been made to improve cell performance and stability for long term operation, SOECs still face challenges to extend cell life. Long term stable operation is necessary for commercialization of SOECs. This study investigates infiltration of the fuel electrode using the nanocatalyst gadolinium-doped ceria (GDC) as an option to further improve cell performance by mitigating Ni coarsening, a known degradation mode of the fuel electrodes, as well as adding robust reaction sites to improve cell performance for longer term operation. Quantitative microstructural analysis is performed on baseline and GDC-infiltrated cells after 500hrs of SOEC operation. The GDC-infiltrated electrode demonstrates mitigated loss of reaction sites and significantly less performance degradation over the testing period.
Proceedings Inclusion? Planned:
Keywords High-Temperature Materials, Characterization, Energy Conversion and Storage

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Journey through New Research Applications in High Temperature Electrochemistry
Analysis of Operating Parameters Affecting SOEC Performance
Assessment of Phase Evolution and Cycling Performance for the Li-Sb-Sn Liquid Metal Battery System with Mixed Cation Molten Salt Electrolytes
Combination of Electrolysis and Thermocatalysis for Dry Reforming of Methane in a Liquid Alloy-salt Catalytic System
Considerations for Measuring High Electrical Conductivity Molten Salts with Concentric Electrodes
Degradation Mechanisms and Mitigation Strategies of YSZ Membranes in Contact with Oxy-Fluorite Flux
Dissolution and Diffusion of Titanium in Liquid Tin and Electrochemical Behavior of Ti-Sn Alloy Separation in Molten Salt
Dynamic Operation of Metal-supported Solid Oxide Electrolysis Cells
Electrically-enhanced Boron and Phosphorus Removal from Silicon by CaO-SiO₂-Al₂O₃/-MgO Slag Treatment
Electrically Enhanced Metal Refining Using Slag – Recent Developments and Future Outlook
Electrochemical Attempts in Molten Salts for Extraction, Recycling, and Synthesis
Electrochemical Recovery of Rare Earth Elements from Magnets in Molten Salts
Electrode Processes of Reactive Rare-earth Metals and Alloys in Molten Salt Electrolytes
Examples of High Temperature Electrochemical Research
High-Throughput Measurement Techniques for Physical Properties of Molten Salt
High Performance Battery Materials from Sustainable Sources
Highly Active and Thermally Stable Single-atom Electrocatalysts for High-temperature Solid Oxide Cells
Improving Performance and Durability of Intermediate Temperature Proton‐conducting Solid Oxide Electrolysis Cells via Materials Design and Catalyst Surface Engineering
Mitigating Fuel Electrode Degradation in SOECs by Infiltrated of Nanoscale GDC Catalyst
Mixed Ionic and Electronic Conductors for Reactive Separation of Hydrogen
On Electrochemically Driven Phase Change and Accelerated Test Protocols in Solid Oxide Cells
Processing Contributions to the Conduction Variability of Sr2-xVMoO6-δ
Production of Pure Aluminum and Oxygen by Solid Oxide Membrane-based Electrolysis Using an Inert Anode
Quantitatively Relating Reaction Site Density and Performance in Electrocatalyst-infiltrated Ni-YSZ Symmetric Cells
Recycling EOL-LIB’s Using Thermokinetic Fundamentals in the LIFE Process for Sustainable Metallurgy
Taking SOM to the Moon: A Lunar Demonstrator for Oxygen and Metals Extraction from Regolith Based on the ROXY Process
The Effect of A-site Doping Elements and Concentrations on the Diffusivity and Ionic Conductivity of La2NiO4+δ Studied by Ab Initio Calculations
The Effect of Temperature on Electrodeposition Behavior of Cobalt from Cobalt Chloride Using 2:1 Urea/ ChCl Ionic Liquid
The Long Road to SOM Primary Magnesium Production
Transforming Residues to Resources and How Sustainable Metallurgy Can Set the Example
Transport Modeling in High-temperature Electrochemical Systems
Unraveling the Essence of Welding Flux Sustainability Towards High Heat Input Applications

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