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Meeting 2021 TMS Annual Meeting & Exhibition
Symposium Coatings and Surface Engineering for Environmental Protection III
Presentation Title Effects of Heat Treatments, Current Density, and Electroless Ni Layer Thickness on Corrosion Performance of Trivalent Chromium Passivations on ZnNi Coatings
Author(s) Kevin L. Foster, William G Fahrenholtz, Matthew J O'Keefe, James Claypool
On-Site Speaker (Planned) Kevin L. Foster
Abstract Scope A trivalent chromium based passivation (TCP) and a cobalt-free version of the same passivation (Co-Free) were studied on ZnNi coated, electroless nickel (EN) plated Al 6061-T6 substrates. Each panel had a 5-20 µm EN layer, 150 or 300 A/cm2 current density for plating the ZnNi, and either an 80°C or 191°C heat treatment after passivation. Corrosion performance was evaluated using image analysis of optical micrographs, and electrochemical testing, and ASTM B117 neutral salt spray exposure. Image analysis showed a performance difference between heat treatments, between EN layers with thicknesses >10 µm versus ≤10 µm, and between TCP and Co-Free passivation. Electrochemical testing revealed differences between 80°C and 191°C heat treatments. The results from this study indicate that the corrosion protection mechanisms are more dependent on passivation chemistry than the deposition and post-processing conditions.
Proceedings Inclusion? Planned:
Keywords Thin Films and Interfaces, Characterization, Other

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Cycling Corrosion Testing of Al-Mg Friction Stir Welding Bi-metallic Joints
Dealloying and Passivation of Cu-doped Carbide-reinforced Martensitic Steels in a Sulfuric Acid
Designing Lubricant-impregnated Coatings to Reduce Corrosion and Hydrogen Embrittlement
Effects of Heat Treatments, Current Density, and Electroless Ni Layer Thickness on Corrosion Performance of Trivalent Chromium Passivations on ZnNi Coatings
Effects of Processing Conditions on the Tribocorrosion Resistance of Zr-based Thin Film Metallic Glass Coatings
Electronic Structure Mechanisms to Explain the Onset of Cl-induced Localised Corrosion in Al2O3
Galvanic Corrosion Mitigation by Material and Coating Selection for AZ31B bolt-joined with CFRP
Pitting Corrosion in Powder-processed Aluminum Alloys Containing Quasicrystalline Dispersoids
Revealing the Long-term Growth Kinetics and Morphology of Atmospheric Corrosion Pitting in Aluminum via In-operando Microtomography
Role of Surface Mechanical Attritions Processing Conditions on the Corrosion Behavior of Aluminum 7075 Alloys
The Effect of Surface Treatment on the Formation, Structure, and Chemistry of Protective Oxide Scale on High-temperature Oxidation-resistant Nickel Alloys
Using Mechanical and Ion Polishing to Identify Structural and Chemical Defects for the Pitting Corrosion of a Compositionally Complex Steel

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