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Meeting MS&T23: Materials Science & Technology
Symposium 2023 Undergraduate Student Poster Contest
Presentation Title Thickness Measurement of Gallium Phosphide Films on Silicon Using X-ray Fluorescence
Author(s) Evan Freeland, Donald Windover, Lauren Kaliszewski, Tyler Grassman
On-Site Speaker (Planned) Evan Freeland
Abstract Scope Thin films, with thicknesses ranging from less than a nanometer to hundreds of nanometers, are an integral part of any modern electronic device. A fast and repeatable technique is needed for measurement of film thickness, both post-processing and in-situ during depotision. X-ray fluorescence (XRF) is a promising technique for this role. By measuring fluorescence intensity for films of varying thicknesses and plotting the results against thickness measurements from an SI-traceable method, a calibration curve can be constructed and used to assess the thickness of unknown films. In this study, a series of heteroepitaxial GaP films on Si substrates were characterized with XRF. XRF maps were produced to study thickness heterogeneity. High-precision measurements were taken with X-ray reflectivity. Between thicknesses of 40 and 500 nm, the Ga line intensity is found to be proportional to the thickness measured by XRR, yielding a simple and readily accessible determination of thickness via XRF.

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