|About this Abstract
||2021 TMS Annual Meeting & Exhibition
||Alloys and Compounds for Thermoelectric and Solar Cell Applications IX
||The Importance of the Mg-Mg Interaction in Mg3Sb2-Mg3Bi2 Shown through Cation Site Alloying
||Max Wood, Kazuki Imasato, Shashwat Anand, G. Jeffrey Snyder
|On-Site Speaker (Planned)
Herein we study the effect alloying Yb onto the octahedral cite of Te doped Mg3Sb1.5Bi0.5 has on transport and the material's high temperature stability. We show that the reduction in mobility can be well explained with an alloy scattering argument due to disrupting the MgOctahedral-MgTetrahedral interaction that is important for placing the conduction band minimum at a location with high valley degeneracy. We note this interaction likely dominates the conducting states across n-type Mg3Sb2-Mg3Bi2 solid solutions and explains why alloying on the anion site with Bi isn't detrimental to Mg3Sb2's mobility. We conclude showing that while the material's figure of merit is reduced with the addition of Yb alloying, its high temperature stability is greatly improved. This study demonstrates a site-specific alloying effect that will be important in other complex thermoelectric semiconductors such as Zintl phases.