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Meeting MS&T23: Materials Science & Technology
Symposium The American Ceramic Society Journal Awards Symposium
Presentation Title NZSP-MS/PEO-NaBF4 Ceramic-polymer Composite-electrolyte for Conformal Solid-state Na-ion Batteries
Author(s) Sushmita Dwivedi, Sudharshan Vasudevan, Palani Balaya
On-Site Speaker (Planned) Palani Balaya
Abstract Scope Conformal solid-state batteries (CSSB) facilitate utilization of various energy storage systems in electric vehicles due to enhanced durability/flexibility. Designing ceramic-polymer composite electrolyte is essential to develop CSSB due to synergistic effect of increased conductivity and high flexibility of composite electrolyte. Also, Na-ion batteries are seen to be potential alternatives to conventional Li-ion batteries owing to abundance and low cost of sodium compounds. Present work focuses on developing a novel NZSP-based ceramic electrolyte with co-doping of Mg and Sc with different concentrations and implementing the best suitable material to fabricate polymer-ceramic composite electrolyte. The composite containing 20wt% polymers with σb ~ 2.04×10^-4 S/cm along with decent ceramic-polymer interfacial ionic conductivity (σi) 4.20×10^-5 S/cm was characterized for Na stripping/plating tests at 100ľA/cm2. These findings shed light on prospects of conformal composite-electrolyte with “polymer in ceramic” electrolyte model to circumvent the challenges of the conventional solid ceramic or polymer electrolyte batteries.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

2nd Century Trailblazers Award Lecture: Mechanical Tailoring of Dislocations in Ceramics at Room Temperature: A Perspective
NZSP-MS/PEO-NaBF4 Ceramic-polymer Composite-electrolyte for Conformal Solid-state Na-ion Batteries
SiOC-based Strain Gauge with Ultrahigh Piezoresistivity at High Temperatures
Synchrotron X-ray Multiscale Tomography: Visualization of Heterogeneous Microstructures, Defects, and Microfractures in Ceramics
Vacancy Ordering in Substoichiometric Zirconium Carbide
Vibrational Spectroscopy Analysis of Silica and Silicate Glass Networks

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