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Meeting 2025 TMS Annual Meeting & Exhibition
Symposium Additive Manufacturing of Refractory Metallic Materials
Sponsorship TMS Structural Materials Division
TMS: Additive Manufacturing Committee
TMS: Refractory Metals & Materials Committee
Organizer(s) Fernando L. Reyes Tirado, Nasa Marshall Space Flight Center
Omar Mireles, Los Alamos National Laboratory
Faramarz Zarandi, RTX Corporation
Jeffrey W. Sowards, NASA Marshall Space Flight Center
Antonio J. Ramirez, Ohio State University
Eric Brizes, NASA Glenn Research Center
Eric A. Lass, University of Tennessee-Knoxville
Matthew G. Osborne, Global Advanced Metals
Joao Pedro Oliveira, Faculdade Ciencias Tecnologias
Ian Mccue, Northwestern University
Zachary Sims, Small Business Consulting Corporation
Scope As the metal Additive Manufacturing (AM) technology evolves and is showing itself as a technically and economically viable option for actual component production, the technology boundaries are being expanded towards more challenging materials, like refractory metallic materials, both alloys, and pure metals. As manufacturing involving refractory alloys has been a persistent challenge, the use of additive manufacturing for the production of complex parts presents itself as a potentially economically viable alternative, and for some key applications, AM seems to be one of the few options available. As a consequence, the exploration and development of metal additive manufacturing of alloys based on W, Mo, and Nb, among others, has attracted many researchers and organizations and this symposium would allow them to share their work, achievements, and challenges while enabling the researchers and engineers to clearly understand the state of the art, the current limitations and the path forward to address such.

The growing interest and research activity on AM for refractory alloys has been driven in part by the growing interest in high-performance turbine engines, hypersonic technology for many defense and commercial applications, in addition to space power generation, and the need to implement nuclear propulsion for long-range space exploration. However, many other applications involve these materials, like the production of superconductive resonance cavities for particle accelerators and even quantum computing.
Refractory metals present unique inherent challenges like elevated reactivity, low ductility, and of course high melting temperatures. As a result, the printing of these materials has shown to be quite challenging. For example, W is known for having an elevated ductile-to-brittle transition temperature what makes powder-bed fusion printing of this material complicated due to severe interconnected microcracking. Developments have been proposed using preheating to elevated temperatures to minimize cracking while printing of refractory alloys, which further enhances oxidation. Other approaches like alloy re-designing and smart thermal engineering during printing could be the solution and several researchers are working on it. Some of the cracking phenomena associated with printing are still unclear and therefore robust solutions have been elusive. Finally, the final obtained microstructures from AM, are unique in several aspects and their influence on performance has also been a matter of study. Therefore, this symposium will bring together the additive manufacturing community that has engaged in the fundamental and applied aspects associated with refractory metals printing. A large and diverse participation is expected from industry, government agencies, national laboratories, and university researchers. The topics of interest include, but are not limited to:

• The varied and complex cracking phenomena associated with solidification and solid-state low ductility on the different refractory alloy systems during AM;
• Alloy elements and impurities effect on refractory alloys printability;
• Alloy design for improved printability and performance of refractory alloys.
• Powder feedstock development advances for AM of refractory metals
• The use of conventional and advanced phase transformation models on the design and optimization of refractory alloys is better suited for different AM processes.
• Relationships between solidification structure, impurities segregation, solid-state crystallographic structure, and defect formation during additive manufacturing and the use of fundamental understanding to propose engineering solutions;
• Modeling and simulation of the printing process and phase transformations associated with AM refractory alloys;
• Specific applications or development/testing of key components.
• Joining techniques and characteristics related to AM refractory metals.

This would be the 4th symposium dedicated to this topic. The first three symposium have been well attended with more productive discussions arising for year to year. With increasing interest in refractory metals and further advancement in AM technologies, it is expected that the fourth symposium in TMS 2025 will provide even more extensive knowledge to help overcome existing challenges.

Abstracts Due 07/15/2024
Proceedings Plan Planned:
PRESENTATIONS APPROVED FOR THIS SYMPOSIUM INCLUDE

A Comparison of Niobium Alloys C103 and Nb521
A new angle to view the battle with oxygen in Molybdenum (Mo) laser powder bed fusion (LPBF)
Additive Manufacturing and High-Temperature Mechanical Behavior of High-Performance Refractory Alloys
Additive Manufacturing Informed Tantalum Alloy Development
Alloy design and microstructure-property relationships for non-equiatomic Ti-Zr-Nb-Ta-V-Cr alloys with tensile ductility made by laser powder bed fusion
Atomistic and Phase Field Simulations of Rapid Solidification Towards Refractory High Entropy Alloys
Computational Design of Graded Refractory Metal Structures
Custom Refractory Alloy Synthesis and Processing
Dense and crack-free pure tungsten manufactured by Electron Beam Powder Bed Fusion using chemically reduced powder
Design and development of a reduced cost, Hf-free Nb-based alloy for additive manufacturing guided by CALPHAD
Design and development of a refractory complex concentrated alloy for additive manufacturing of advancing space propulsion components
Development of Molybdenum Alloys for Use with Powder Blown Laser Direct Energy Deposition Additive Manufacturing
Direct energy deposition of tungsten by high repetition high power femtosecond laser
Directed Energy Deposition of Vanadium for Interlayers in Laser Welding
Effects of Oxygen Concentration in Ductile to Brittle Transition Temperature (DBTT) of Niobium C103 Fabricated via Laser Direct Energy Deposition.
Elevated Temperature Mechanical Performance of Historical Niobium Alloys
Elevated Temperature Testing of LP – DED C103 Thin Wall Structures
Enhanced Development of Tungsten Alloy Plasma Facing Materials
Exploring Fabrication pathways, Phase evolution and Structure-Property Relationships in High Temperature Functionally Graded Material
Hafnium-based refractory high entropy alloy structures produced via additive manufacturing for extreme temperature applications
High-throughput refractory alloy design for additive manufacturing
High temperature mechanical properties of laser powder bed fusion processed Nb-based C103 alloy
Hot-fire Testing of C103 Nozzle Extensions
Impact of Ceramic Nanoparticle Additions on the Properties of Additive Manufactured Refractory Metals
Impact of multi-scale microstructural heterogeneities on the mechanical behavior of additively manufactured and post-processed Nb-based C103 alloy
Impact of Stochastic Scanning Strategies in Electron Beam Powder Bed Fusion of Tungsten Alloys
Joining Niobium Refractory Alloy with Titanium Alloy in Direct Energy Deposition Additive Manufacturing Process
Laser Assisted Additive Manufacturing of W and W-Re for Fusion Power Application: Material Response in Manufacturing Environment
Laser Powder Bed Fusion of C103 and Refractory-based Alloys - Material Development Using Ultrasonic Atomization
Microstructural evolution and mechanical properties of additively manufactured W-Ta alloys
Microstructural Evolution in Laser Powder Bed Fusion Processed W and W-Re
Process-structure-property relationships of additively manufactured refractory metals
Prototype elements manufactured from molybdenum and tungsten modified with rhenium using LPBF technology
Reactive synthesis in additive manufacturing of an ultrahigh-temperature Mo-Si-B-Ti alloy
Solid State Additive Manufacturing of Refractory Alloys using Cold Spray Technology
Thermo-mechanical Testing Approach of Additive Manufactured Ultra-High Temperature Refractory Alloys
Thermomechanical Model Based Approach to Mitigate Crack Susceptibility in Additive Manufactured Refractory Material.
Uncovering the Ultra-high Temperature Deformation Mechanisms of Novel Refractory Alloys
Understanding the Elevated Temperature Properties of Niobium-Based Alloys Relevant to Aerospace Applications
WC-based functionally graded materials fabricated by laser powder Directed Energy Deposition


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