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Meeting MS&T21: Materials Science & Technology
Symposium Progressive Solutions to Improve Corrosion Resistance for Nuclear Waste Storage
Presentation Title A Geopolymer for Hanford Secondary Waste
Author(s) Sepideh Akhbarifar, Weiliang Gong, Werner Lutze, Ian L Pegg
On-Site Speaker (Planned) Sepideh Akhbarifar
Abstract Scope Preceding this work, a geopolymer was developed at CUA to solidify ‘Hanford Secondary Waste’, which contains low levels of hazardous metals, 99Tc, and 129I. All waste elements were fixated at least as well as in other candidate waste forms. Scale-up testing revealed that using only two pozzolans (slag and metakaolin) to make the geopolymer limited desirable ranges of rheological properties and set times for large-scale production. Including a third pozzolan (fly ash) provided sufficient flexibility. We report on a quantitative evaluation of the rheological properties and set times of geopolymers made with the three pozzolans. The rheological set time will be compared with that of the Vicat tests. The composition dependence of compressive strength will be discussed. Expecting that a fast-growing fraction of electricity will be produced from renewable sources and the continuing use of nuclear power, the already very low CO2 footprint of geopolymers will approach zero.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Geopolymer for Hanford Secondary Waste
Introductory Comments
Neutron Microscope Based on Wolter Optics for Imaging Hydrogen Distribution in Glass
Particulars of Crystallization of Glass-ceramics for Nuclear Waste Storage
Predicting Zeolites’ Stability during the Corrosion of Nuclear Waste Immobilization Glasses
Understanding Corrosion of Nuclear Waste Glasses through Molecular Dynamics Simulations and Quantitative Structural Property Relationship Analysis
Using Stress Modelling to Understand Effects of Pit Morphology on Stress Corrosion Cracking Initiation in Austenitic Stainless Steels

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