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Meeting 2022 TMS Annual Meeting & Exhibition
Symposium Environmental Degradation of Multiple Principal Component Materials
Presentation Title Corrosion Interactions between a Candidate Hollandite Waste Form and Stainless Steel
Author(s) Chandi Mohanty, Keith Bryce, Xiaolei Guo, Kun Yang, Jie Lian, Jianwei Wang, Gerald Frankel
On-Site Speaker (Planned) Chandi Mohanty
Abstract Scope The static leaching characteristics of Ba from barium hollandite with targeted composition BaFe2Ti6 O16 was studied in intimate contact with stainless steel (SS) 316L in a 0.6M NaCl solution. The synthesized hollandite waste form was characterized by XRD, Raman spectroscopy and SEM. Localized corrosion of SS enhances the leaching of the hollandite waste form by creating a low pH environment in the tight crevice formed between the two materials. The corroded hollandite surface consists of a discontinuous and highly porous Fe-Ti rich layer with minor amounts of Ba. Raman spectroscopy shows that hollandite leaching leads to an increase in the amount of rutile phase due to preferential leaching of Ba from the A site. Evidence from XPS shows the oxidation of Ti3+ to Ti4+ with breaking of the A-site channel, which facilitates Ba leaching.
Proceedings Inclusion? Planned:
Keywords Ceramics, Nuclear Materials,

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

B-1: Evaluating the Influences of Microstructural Attributes on the High Temperature Oxidation of a AlCoCrFeNi High Entropy Alloy
Computational Investigation of the Trends that Govern the Coefficient of Thermal Expansion in Rare-earth Silicates
Corrosion Interactions between a Candidate Hollandite Waste Form and Stainless Steel
Corrosion Resistance of Al-Cr-Ti Containing Compositionally Complex Alloys
Development of a New Aluminum Dissolvable Alloy for Hydraulic Fracturing Applications
Dynamic and Chemical Processes Associated with Deposit-induced Corrosion Testing at Elevated Temperatures
Enhanced Oxidation Resistance of (Mo95W5)85Ta10(TiZr)5 Refractory Multi-principal Element Alloy up to 1300C
Equivalent Hydrogen Fugacity during Electrochemical Charging of Nickel Single Crystal: Comparison with Gaseous Hydrogen Charging
Experimental and Numerical Assessment of the Corrosion Behavior of a Friction Stir Processed Equiatomic CrMnFeCoNi High Entropy Alloy in a Neutral Environment
Exploring Hydrogen-induced Martensitic Transformation and Twinning Effects Metastable Fe-Mn-Co-Cr High Entropy Alloys
Exploring Untapped Potential in High Entropy Alloys: Combinatorial Exploration in Corrosive Environments
Hydrogen Embrittlement Behavior of Face-centered Cubic High-entropy Alloys
Investigation of Low Temperature Oxidation Behavior of MoNbTaW Thin Films
Joining of FeCrAl Based Alloys for Lead Cooled Fast Reactor Applications
Localized Corrosion Resistance of Ni-Cr-Co-Fe-Mo MPE Alloys in Aqueous and Methanolic Environments
Machine Learning Potential for High Entropy Alloys
Microstructure and Corrosion of Multi-phase Ni-Fe-Cr-Mo-W-X Multi-principal Element Alloys
Modeling and Design of CoCrFeNi Multi-principle Element Alloys on Their Aqueous Corrosion Resistance via First Principle Calculations
Modeling Preferential Dissolution during Aqeous Corrosion of Multi-principal Element Alloys
NOW ON-DEMAND ONLY – Interpretable Machine Learning to Understand Corrosion in Complex Compositional Alloys
Optimization of Multicomponent Rare Earth Silicate Environmental Barrier Coating Properties
Oxidation of Different High Entropy Alloys Under the Influence of Water Vapour
Oxygen Modulation of Miscibility and Ordering in BCC Nb-Ti-Zr Alloys
The Tribocorrosion Behaviors of Al0.1CrCoFeNi Multi-principal Element Alloys in Different pH Conditions

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