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Meeting 2020 TMS Annual Meeting & Exhibition
Symposium Hume-Rothery Symposium: Thermodynamics, Phase Equilibria and Kinetics for Materials Design and Engineering
Presentation Title Thermodynamic Assessment of the Fe-B and Fe-B-C- Systems
Author(s) Katsunari Oikawa, Nobufumi Ueshima
On-Site Speaker (Planned) Katsunari Oikawa
Abstract Scope Born is added to improve the mechanical strength through enhancement hardenability by segregation to grain boundary. While, boron forms the borocabide as well as boride in the steels. These precipitates have harmful effect on the mechanical properties. To understand the behavior of boron and carbon in the steel, phase diagrams of Fe-B-C system are essential information. In this study, the phase equilibrium of the Fe-B and Fe-B-C systems were investigated using diffusion couple method and DSC. Furthermore, thermodynamic assessment of these systems was carried out by using the CALPHAD method. In the Fe-B-C system, the solubility of carbon in liquid and fcc phases was decreased with increasing boron content. The assessment also predicted the metastable two-liquid phase separation in Fe-Fe2B region. This phase separation might be the origin of two-phase separation of the Fe-B base amorphous. These results are very useful to understand the effects of boron on the steel.
Proceedings Inclusion? Undecided

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Hexagonal Close Packed Multi-principal-element Alloy Identified Computationally
Alloys, Processing, Applications, Models and Software: The Wide Domain of Gibbs Energies Sets Giving Impulse to Invention
Application of Calphad-based Computational Tools to Alloy Development for Additive Manufacturing
Calphad Applications and Challenges in Gas Turbine Coatings
CALPHAD Databases for Co-based Alloys
Computational Thermodynamics in Microstructure Modelling and Beyond
Developing CALPHAD Databases for Thermophysical Properties of Metals and Alloys
Development of a Comprehensive Diffusion (mobility) Database for Lightweight Magnesium Alloys
Diffusion Mobilities in Co-Ni-Al-Cr System
First-principles Thermodynamics of Refractory Alloys and their Oxides
How Can the CALPHAD Method Do Better?
Improvement of a CALPHAD Database for the Development of Next Generation TiAl Alloys by Targeted Key Experiments on High-temperature Phase Equilibria – The EU Project Advance
Industrial Applications of Thermodynamic and Kinetics Modeling
Interaction of Moving Grain Boundaries with Solutes in Alloys
Materials Property Databases Developed by the CALPHAD Approach and Their Applications in Materials Design
Measurements of Thermophysical Properties of Metals and Alloys as Input for Computational Thermodynamics
On the Intrinsic Alloying Behavior in the A and M Sublattices of MAX Phases
On the Next Generation of Thermodynamic CALPHAD Databases
Phase Equilibria and Interfacial Migration in Stressed Solids
Phase Equilibria in High-entropy and Complex-concentrated Alloys
Selected Observations of Microstructural Development in Additively Manufactured Metallic Alloys
The Application of Metastable Equilibria in the Analysis of Transformation Behavior
The Third Generation of CALPHAD Descriptions: Case Studies on Al-C and W-C
Thermodynamic Assessment of the Fe-B and Fe-B-C- Systems
Thermodynamic Modeling of Precipitates of Topologically Close-packed Phases
Thermodynamics at Equilibrium and Non-equilibrium – Genomic Tools for Materials Design
Tomorrow fcc Ordering Model
William Hume-Rothery Award Lecture: Phase Diagrams, Computational Thermodynamics and CALPHAD

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