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Meeting Materials Science & Technology 2020
Symposium Thermodynamics of Materials in Extreme Environments
Presentation Title Thermodynamics and Elastic Properties of Cerium Doped Yttrium Aluminum Garnets
Author(s) Vitaliy G. Goncharov, Nian Wei, Miu Lun Lau, Albert Migliori, Hongwu Xu, Min Long, Xiaofeng Guo
On-Site Speaker (Planned) Vitaliy G. Goncharov
Abstract Scope Cerium doped yttrium aluminum garnet (Y3-xCexAl5O12, Ce:YAG) is a promising yellow-light emitting component of solid state white-light emitting diode. In this work, we investigate the effects of Ce doping on the elastic properties of Ce:YAG. Resonant ultrasound spectroscopy (RUS) was employed to determine the elastic constants of Ce:YAG at x = 0.025, 0.1 and 1 at. %. Through the calculation of elastic moduli and utilization of the Mie-Grüneisen EOS approach Cp at room temperature was successfully obtained for Ce:YAG. Debye Temperature (𝜃𝐷) was determined with RUS measured sound velocities and was in excellent agreement to values obtained from neutron scattering and theoretical methods. Lastly, RUS application and reliability towards extrapolation of further thermodynamic parameters is discussed.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Ab-initio Studies of Point Defects in Alumina under Electrochemical Conditions
Density Functional Theory Modeling on the Positive Effect of H2O in Hydrogen Oxidation Reaction on Perovskite Anode for Solid-oxide Fuel Cells
Effect of Physically Determined Coordination-numbers for Modeling Molten Salt Fuels Using the Modified Quasi-chemical Model (MQM)
Ellingham Diagram to Assess Synthesis Conditions and Chemical Stability of Ceramic Membranes under Operational Conditions
Exploring Extreme Environments via In-situ Electron Microscopy
Helium Irradiation of Gd2Zr2O7 Defect-fluorite Ceramics: Interfacial Phenomena and Radiation Resistance
Improved CMAS Resistance of Environmental Barrier Coatings via Tailoring Phase and Composition of Mixed Rare Earth Silicates
Molecular Modeling of Surface Exchange Mechanisms in Solid Oxide Fuel Cell Cathodes
Nanomaterials from Geopolymer, a Low-temperature Ceramics
Pressure-induced Anomalous Phase Transition Behavior in Layered Tellurene
Stabilities and Ultrafast Dynamics of Sub-nanometer Metal Oxide Clusters
The LiF–ZrF4 System Revisited - An Updated Thermodynamic Description Using New Information Data
Thermochemical Modeling of Molten Salt Systems for Reactors and Simulations with the Molten Salt Thermodynamic Database
Thermodynamic Modelling of Vacancies in Zirconium Carbide
Thermodynamics and Elastic Properties of Cerium Doped Yttrium Aluminum Garnets

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