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Meeting 2021 TMS Annual Meeting & Exhibition
Symposium High Temperature Electrochemistry IV
Presentation Title High-speed Electrodeposition of Textured Monolithic Lithiated Transition Metal Oxide Cathodes for Low Cost, High Energy, and Fast Charging Li-ion Batteries.
Author(s) John Cook
On-Site Speaker (Planned) John Cook
Abstract Scope Xerion Advanced Battery Corp, founded in 2010, is in the process of commercializing a single-step molten hydroxide electroplating process to manufacture lithiated transition metal oxide (LTMO) cathodes. Xerion’s process benefits from the combined synthesis and electrode formation in just one step – revolutionizing the current commercial slurry-electrode manufacturing process (>20 steps). In this talk, the importance of crystal texture will be discussed. Xerion has found that controlling the crystal orientation improves the fast charge performance and delays the onset of thermal run-away. Furthermore, a business case will be provided for the use of LCO for automotive applications despite the current opinion that LCO is too expensive outside of the consumer electronic space. Xerion’s cost models show, at scale, our process can produce LCO / graphite cells at $45/kWh by utilizing low purity lithium and cobalt sulfate as opposed to battery grade >99.5% purity precursors.
Proceedings Inclusion? Planned:
Keywords Copper / Nickel / Cobalt, Energy Conversion and Storage, Characterization

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Comparative Study of Working Electrode Materials for Voltammetry Measurements in LiCl–Li2O Salts
Advances in Solid Oxide Membrane Based Electrolysis for Solar-grade Silicon Deposition
Effect of Hydroxide and Oxide Impurities in Electrochemical Processes Using Molten LiCl and CaCl2
Electrochemical Reactions of Oxide Ions with Tungsten in Molten CaCl2
Feasibility of Potentiometry for Monitoring Activity of GdCl3 in Molten LiCl-KCl Salt
First-principles Molecular Dynamics and CALPHAD Modeling of the CaF2-MgF2-SiO2 Molten Salt System
Fundamental Challenges for the Development of Electrolytic Reduction of Uranium Oxide in Molten LiCl-Li2O
High-speed Electrodeposition of Textured Monolithic Lithiated Transition Metal Oxide Cathodes for Low Cost, High Energy, and Fast Charging Li-ion Batteries.
Interaction between Solute Species and Metallic Alloying Elements in Molten Chloride Systems
Investigation on Preparation of Fe-Al Alloys by Direct Reduction of Fe2O3-Al2O3 Powder in CaCl2-NaCl Molten Salt System
Liquid Bipolar Electrode for Extraction of Aluminium and PGM Concentrate from Spent Catalysts
Molten Hydroxide Mediated Electrosynthesis of Layered Transition Metal Oxides for Electrochemical Energy Storage
New Electrochemical Deoxidation Method of Ti Metal in Molten Salts Containing YCl3
Optimizing Reaction Selectivity in High Temperature Molten Electrolytes
Selective Extraction of Gold from Gold-copper Alloy Using Anodic Electrochemical Deposition in Molten Salt Electrolyte
Validated Modeling of Quartzite Reduction to Solar Silicon by Molten Salt Electrolysis

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