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Meeting 2023 TMS Annual Meeting & Exhibition
Symposium New Directions in Mineral Processing, Extractive Metallurgy, Recycling and Waste Minimization: An EPD Symposium in Honor of Patrick R. Taylor
Presentation Title Energy Storage and Recovery Employing Iron-Iron Oxide System as an Electrofuel
Author(s) Uday Bhanu Pal, Hadassah Elizabeth Flagg, Haoxuan Yan, Achim Seidel, Georg Poehle, Christian Redlich
On-Site Speaker (Planned) Uday Bhanu Pal
Abstract Scope Electrofuels produced using renewable energy are the desired energy carrier for a carbon-free society. Iron powder produced electrolytically from iron oxide is an Electrofuel having high-energy density. They can be combusted to their oxide to release the chemical energy at different scales comparable to fossil fuels but without the harmful emissions. In this work we investigate a novel method of electrolytically reducing the iron oxide back to iron employing solid oxygen-ion conducting membrane (SOM) cell with liquid silver as the reducing medium. Liquid silver with the iron oxide is contained in the SOM cell, and the soluble oxygen is pumped out of liquid silver with a system of electrodes to generate the required reducing conditions. Since iron and liquid silver have no mutual solubility, the reduced iron is easily separated employing magnetic means. Details regarding cell design, electrode choices, and product characterization will be presented along with cell performance.
Proceedings Inclusion? Planned:
Keywords Energy Conversion and Storage, High-Temperature Materials, Characterization

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Kinetic Description of Physico-chemical Processes Taking Place in the Burden of HCFeMn Submerged Arc Furnaces
A Multi-scale View of Scalability Challenges in Hydrogen-Based Ironmaking
Alternative Fluxes for Lead Bullion Refining
Alternatives to Pyrometallurgical Recovery of Copper and Gold from Waste Printed Wiring Boards: Process Flow and Environmental Impacts Assessment
Application of Fiber Optics in Metallurgical Processes Temperature Monitoring of Metallurgical Furnace with Distributed Temperature Sensing (DTS)
Art + Engineering at South Dakota Mines
Comparison of Hydrogen Reduction of Different Lead-bearing Materials for Lead Recovery
D-26: Critical Review of Chemical Metallurgy of Tungsten
D-28: Estimated End-of-life Lithium-ion Battery Resources for Potential Recycling in Bangladesh
D-29: Gravity Driven Multiple-effect Thermal System (G-MET) Distillation for Continuous Efficient Lead Refining
D-30: In-situ Microscopy Observations of Oxide Phases Formation during High-temperature Oxidation of End-of-life Ni/Cu/Ni-coated-NdFeB Permanent Magnets
D-31: Introducing Membrane Percrystallisation Technology for Hydrometallurgical Applications
D-32: Investigating the Influence of Temperature and Atmosphere on the Formation and Decomposition of PAHs from Carbonaceous Materials Used in Industrial Processes: Method Development
D-33: Rare Earth Reduction – A Technological Overview of State-of-the-art Technology and Novel Developments
D-34: Recovery of Bismuth in Blast Furnace Dust by Carbothermal Volatilization Reduction
D-35: Recovery of Valuable Metals from Li-ion Battery Waste through Carbon and Hydrogen Reduction: Thermodynamic Assessment and Experimental Verification
D-36: SPYRO: Share Skills and Good Practices in PYROmetallurgy
D-41: Solar Thermal Application in Zn/ZnO Recovery from Spent Alkaline Batteries
D-45: Removal of Iron from an Electrolytic Solution Rich in Copper by Selective Hydrometallurgical Routes
Decarbonizing Steelmaking: Nanoscale Mechanisms in H2-Based Reduction of Iron Oxides
Development of Dynamic Model of Collision and Coalescence for Molten Matte Droplets in Copper Smelting Reaction Shaft Considering Interfacial Deformation
Development of Ironmaking Technology by the Direct Gaseous Reduction of Iron Concentrate
Domestic Strategic & Critical Metal & Material Production With NSC & ASL Hydrometallurgical Technologies.
Electrochemical Mining of Municipal Solid Waste Incinerator Ashes
Electrochemical Splitting of Salt Bearing Effluents
Electrowinning Impurities Out of Flowing Molten Chloride Salt for Heat Transfer Fluid Applications
Energy Storage and Recovery Employing Iron-Iron Oxide System as an Electrofuel
Enhancing Performance in Hydrometallurgical Extraction, Separation, and Recovery of Metals
EPD Distinguished Award Lecture: New Directions for Biotechnology Practices in Metals Extraction
Evaluating Waste Reprocessing: Framework Development
Examples of Innovations in Metallurgical Engineering Education and Curriculum Development at the University of Utah
Extractive Metallurgy Education – On the Rim of Extinction or in the Beginning of a New Era
Ga, In and Ge Extraction from Zinc Plant Residues by Chlorine Metallurgy
High Vacuum Solar Thermal Dissociation for Metal and Oxide Extraction
Investigation of Cerium, Terbium, and Lantanium Dissolution Parameters in Fluorescent Wastes by Microwave Leaching
Investigation of Heavy Metal Levels in Tin Mine Wastes and the Implication to Mine Closure Plan: A Case Study of Rutongo Mine, Rwanda
Kinetic Study of Reduction of ZnFe2O4
Lanthanum-light Metal Alloys Production using Secondary Resources - Thermodynamic Analysis
Leaching of Arsenopyrite Contained in Tailings Using the TU-OX System
Lead Bleed-off from Dust of Copper Smelter
Mixture Solidification Model for Simulation of Freeze Lining
Nano-/Superfine Metallic Particles from Waste Printed Wiring Boards: A Cradle-to-gate Sustainability Assessment
NbC-containing High Carbon Steel Grinding Media Development
New Directions in Decarbonization of Metals Production
Nickel Matte as Novel Reductant in Galvanic Leaching of Spent Lithium-ion Battery Black Mass
Open Innovation in Battery Recycling R&D
Options for Sustaining Metallurgical Engineering Education
Rare Earth and Critical Base Metals Electrodeposition using Urea - Choline Chloride Ionic Liquids
Recyclability of Proton Exchange Membrane Electrolysers for Green Hydrogen Production
Recycling End-of-Life Acrylonitrile Butadiene (ABS) as Reductant for Metallic Iron Production from the Opon Mansi Iron Ore
Recycling of Spent Lithium-ion Batteries at Swerim
Requirements for an Extreme Make-over of the Metals Industry
Research and Industrial Application of Selenium and Tellurium Recovery Processes
Selective Chlorination as an Innovative Extraction Method for Valuable Metals from Iron Containing Matrix
Sensor-based Sorting. A New Workhorse in the Recycling and Mining Community
Separation of Copper in Steel Scarp for Recycling
Separation of Li and Co from LiCoO2 Cathode Material through Aluminothermic Reduction Using Different Aluminum Sources: Chemical Grade, Swarf, and Dross
Simulation and Post Mortem Studies: The Holistic Approach for Optimized and Engineered Lining Concepts
Simultaneous Deposition of Nickel and Electrolytic Manganese Dioxide
Solid Oxide Membrane-based Electrolytic Process for the Conversion of Lunar Regolith to Oxygen and Metal (ROXY)
The Importance of Autoclave and Piping Materials Selection for HPAL and POX Metals Extraction Processes
Titanomagnetites: Ores of the Future?
Towards Framework Development for Benchmarking Energy Efficiency in Foundation Industries: A Case Study of Granulation Process

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