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Meeting MS&T21: Materials Science & Technology
Symposium Coatings to Protect Materials from Extreme Environments
Presentation Title Effects of Topcoat Modifications on Bond Coat Oxidation, Internal Stresses, and Interface Toughness in Multilayer Si/Yb2Si2O7 Environmental Barrier Coatings
Author(s) Benjamin R. Herren, Chihpin Chuang, Jonathan D Almer, Kang N Lee, Katherine T Faber
On-Site Speaker (Planned) Benjamin R. Herren
Abstract Scope In Environmental Barrier Coating (EBC) systems exposed to high-temperature combustion environments, progressive bondcoat oxidation results in mismatched material properties, internal strains, and ultimately topcoat spallation. Limiting bondcoat oxide growth is thus expected to increase EBC reliability and lifespan. This study examines the effects of modifying topcoat composition on oxide growth and internal stresses in a current (Si/Yb2Si2O7) EBC. Steam cycling simulated the humid, high-temperature engine exposures and was used to assess the compositional effects on thermal oxide thickness, microstructure, and chemistry. Nanoindentation was used to evaluate interface toughness changes with composition and exposure. Synchrotron X-ray scattering and imaging permitted observation of internal strains and damage. By comparing internal strains, associated stresses, microstructure, and interface toughness between modified and baseline EBCs, the influence of topcoat composition and thickness modifications on EBC longevity may be discerned.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Coatings for Improving the High Temperature Oxidation Resistance of Mo-based Systems
Effects of Laser Remediation Treatments on Global vs Local Environmentally-assisted Cracking of 5xxx Series Aluminum Alloy Ship Plate
Effects of Topcoat Modifications on Bond Coat Oxidation, Internal Stresses, and Interface Toughness in Multilayer Si/Yb2Si2O7 Environmental Barrier Coatings
Electrodeposition of Functionally-graded Interlayers for Joining Plasma-facing Components and Heat-sinks for Nuclear Fusion Reactors
Evaluation of YbPO4 as an Environmental Barrier Coating Candidate
Functionally Graded Corrosion Resistant Coatings for Molten Salt Reactor Systems
High Temperature Stability and Decomposition of Mixed Oxide and Sulfate CMFAS-type Deposits and Implications for Coating Degradation
In-Situ Ceramic Oxide Coating on Stainless Steels for Molten Salt Corrosion Prevention for Concentrated Solar Power Applications
Modelling Oxygen Permeability through Top Coat and Thermally Grown Oxide in Dense Yb2Si2O7 Environmental Barrier Coatings
Na2SO4 Interactions with Rare Earth Silicate Environmental Barrier Coatings
Now On-Demand Only - Aerosol Deposition and Characterization of Sodium Niobate
Obtaining Surface Coatings Providing Protection Against High Temperatures in the Production of Coke
Obtaining Surface Titanium Coatings for Enhance the Material Performance in SHS Conditions
Polymorph Stability and Thermal Expansion Tensors of Mixed and High Entropy Rare Earth Disilicates
Protection of Yttria Stabilized Zirconia (YSZ) Surface from CMAS Attack by Sacrificial Layer of Si3N4
Protocol for Selecting Exemplary Silicate Deposit Compositions for Evaluation of Thermal and Environmental Barrier Coatings
Self-generated Tribo-coatings on Glass from Nano-dispersions in Aqueous Medium
The Efficacy of Inorganic Zinc-Rich Primers to Mitigate Stress Corrosion Susceptibility in Al-Mg Alloys
Thermal and Mechanical Properties of Y3(Nb1-xTax)O7 as a Material for Thermal Barrier Coating
Understanding Modes of Mixed Deposit-Induced Degradation on Advanced Alloys and Bond Coat Systems

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