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Meeting 2025 TMS Annual Meeting & Exhibition
Symposium Environmental Degradation of Multiple Principal Component Materials
Sponsorship TMS Structural Materials Division
TMS: Corrosion and Environmental Effects Committee
TMS: Nuclear Materials Committee
Organizer(s) Wenjun Cai, Virginia Polytechnic Institute and State University
XiaoXiang Yu, Novelis Inc.
Vilupanur A. Ravi, California State Polytechnic University Pomona
Christopher R. Weinberger, Colorado State University
Elizabeth J. Opila, University of Virginia
Bai Cui, University of Nebraska Lincoln
Mark L. Weaver, University of Alabama
Bronislava Gorr, Karlsruhe Institute of Technology (KIT)
Gerald S. Frankel, Ohio State University
ShinYoung Kang, Lawrence Livermore National Laboratory
Srujan Rokkam, Advanced Cooling Technologies, Inc.
Scope Multiple principal component materials seek to utilize configurational entropy to stabilize disordered solid solution phases. The most well-known materials in this novel class include multi-principal element alloys (MPEAs), high-entropy alloys (HEAs), and high-entropy ceramics (HECs). The numerous combinations of constituents in such materials represent a huge but under-explored chemical space and offer considerable freedom in the material design. Among a wide range of material properties observed based on the compositions selected and microstructures developed, the exceptional degradation resistance of some MPEAs and HECs suggests potential applications in severe and extreme environments, while others exhibit reduced environmental durability. This variation in behavior demonstrates that gaps in knowledge still exist regarding the effects of individual elements and their combined effects on reactivity. One can expect more complex processes to occur in the multicomponent systems, including selective oxidation and dissolution of various elements, possible nonstoichiometric oxides and nonequilibrium defect formation, and complicated synergies between materials and the environment. For these reasons, the current models lack the capabilities to fully understand and predict degradation processes in multi principal component materials.

This symposium will provide a platform to discuss and present recent experimental investigations on environmental degradation behavior, novel characterization methods development, and advanced theoretical modeling and computational simulation.

Themes of interest include, but not limited to:
(1) Aqueous and high temperature corrosion, oxidation, and electrochemistry studies of multicomponent materials such as high entropy alloys, ceramics, and intermetallic compounds under various corrosive environments.
(2) Thermodynamics and kinetics of formation and growth of secondary phases including oxide and phase separation in multi-principal elements alloys and high-entropy ceramics.
(3) Interaction of mechanical stresses and corrosive environments, such as
stress corrosion cracking, corrosion fatigue, and tribocorrosion.
(4) Interaction of ion irradiation and corrosive environments, such as irradiation affected corrosion and irradiation-assisted stress corrosion cracking.
(5) Hydrogen pick-up and embrittlement.
(6) Degradation of HEAs in molten salts and liquid metals.
(6) In situ and ex situ electrochemical analysis of oxidation and corrosion kinetics.
(7) Advanced characterization on the structure and composition of oxidation and corrosion products.
(8) Multiscale modeling and computational simulation, including density functional theory, molecular dynamics, kinetic Monte Carlo, CALPHAD, and phase-field methods.
(9) High-throughput materials design, synthesis, tests, and characterization.
(10) Database and machine learning model developments in high-entropy alloys and ceramics design.

Abstracts Due 07/15/2024
Proceedings Plan Undecided
PRESENTATIONS APPROVED FOR THIS SYMPOSIUM INCLUDE

A High Throughput CALPHAD development method designing Single Phase Alloy Platform For the Exploration of Light-Weighting Elements' as Passivators in Co-Free FCC Alloys
Alumina-forming Nb-Mo-Ti-Al bond coat alloys
Atomistic Exploration of Orientation-Dependent Tribological Properties of CrCoNiFe at Elevated Temperatures
Corrosion and Passivation of Multi-Principal Element Alloys in Aqueous Solutions
Cyclic Oxidation of NiCoCr Alloys in Air and Air-Steam Environments
Cyclic Oxidation of Oxide Dispersion Strengthened Multi-Principal Element Alloys
Design and evaluation of multicomponent rare earth disilicate environmental barrier coatings
Development of NiCoFeCrAl based high entropy alloys for hydrogen fueled turbine system
Development of Novel Light Refractory Compositionally Complex Alloys for High Energy Accelerator Windows
Discovery of Oxidation-Resistant Refractory Complex, Concentrated Alloys Through High-Throughput Calculations and Experiments.
Exploring the synergistic benefits of Al and Ti addition on aqueous passivation of Cr containing Fe-Cr-Al-Ti alloys.
Future from the Past: Insights from Neutron and X-ray CT on Iron Archaeological Artifacts
Hot corrosion behavior of nickel-based superalloys in molten Na2SO4-MgSO4 salts
Hydrogen Interaction with Stacking Faults in CoCrNiW Alloy: Insights from In-Situ ECCI During Tensile Testing
Hydrogen solution in a TiNbZr medium-entropy alloy
Improvement of complex oxide properties by doping
Influence of the presence of titanium or tantalum on the oxidation behavior at 1200°C of cast Multi-Principal Element alloys derived from an equimolar CoNiFeCr basis
Instrumented indentation studies on the hydrogenated high- and medium-entropy alloys
Investigating the synergistic effects of Al on aqueous passivation of Cr containing [FeCoNi]-CrxAly compositionally complex alloys (CCAs)
Investigation of Corrosion Behavior of FeCoNiCuZn High Entropy Alloy in H2SO4, NaCl, and KOH Electrolyte Solution
Investigation of Electrochemical Behavior of Novel Liquid-Phase Reinforced Cu-Ga-In Ternary Alloys
Investigation of microstructure and irradiation effects in MoNbTi refractory high entropy alloys
Investigation of Protective Potential of Al & Cr in Intermediate Temperature Oxidation of MoNbTaW Thin Film
Metallographic follow-up of the oxidation progress with time of cast Cantor alloys at 1000°C
Optimizing strength-corrosion properties in sulphuric acid environment via tailoring V-Cr composition in medium-entropy VCrCoNi alloys
Oxidation Behavior of High Entropy Materials
Oxidation Mechanisms and Kinetics of Tailored Refractory-Based High Entropy Alloys
Oxidized surfaces and deteriorated subsurfaces of HEAs and MC-strengthened HEAs oxidized at high temperature in presence of water vapor
Passivation Behavior of Fe42Mn28Co10Cr15Si5 High Entropy Alloy
Phase stability and magnetic thermodynamics in rocksalt high-entropy oxides
Predicting alloy oxidation resistance using physics informed machine learning
Probing irradiation response in CrFeMnNi compositionally complex alloys using high-throughput methodology
Recent Updates on Corrosion Behaviors of High Entropy Alloys
Selective Oxidation and Heterogeneous Diffusion in the Initial Oxidation Phase of CoCrFeNi High-entropy Alloy
Strategies for Improved Oxidation Resistance of Refractory Multiple Principal Element Alloys
Understanding corrosion of multi principal element alloys using machine learning


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