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Meeting 2026 TMS Annual Meeting & Exhibition
Symposium Vacancy Engineering in Metals and Alloys
Presentation Title Investigating nanocavity formation kinetics in irradiated materials through elemental segregation
Author(s) Xing Wang, Xingyu Liu, Xinyuan Xu
On-Site Speaker (Planned) Xing Wang
Abstract Scope Energetic particles such as neutrons and ions can generate numerous Frenkel pairs in nuclear materials. Vacancy clustering often leads to the formation of cavities, including voids and gas-filled bubbles, which are key contributors to material swelling. Studying elemental segregation offers valuable insights into the kinetics of cavity formation in alloys. Here we present a case study using ferritic-martensitic (FM) steels. While chromium enrichment is evident at grain boundaries, no such enrichment is observed near nanoscale cavities by either transmission electron microscopy or atom probe tomography. This contrast suggests that chromium enrichment is mainly driven by interstitial-mediated diffusion, which plays a negligible role in nanocavity growth. Additionally, FM steels with higher nickel and silicon contents exhibit slower cavity growth rates and stronger clustering of these elements. Density functional theory calculations confirmed strong binding between vacancies and nickel-silicon clusters, which likely reduces the vacancy flux toward cavities and thus suppressing cavity growth.
Proceedings Inclusion? Planned:
Keywords Characterization, Nuclear Materials, Iron and Steel

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A combined physics-based and data-driven prediction of vacancy formation energies in refractory non-dilute random alloys
Assessing the Mechanical Properties of Iron Aluminides: Strength and Brittle-to-Ductile Transition
Assessing Vacancy-Solute Clustering and Void Nucleation in Magnesium Alloys Via Transition Interface Sampling
Design of radiation-resistant dilute alloys using synergistic solutes to trap vacancies
Direct Simulation of Vacancy Transport During Creep Deformation in Coupled Extreme Environments
Dynamic microstructure stabilization via self-organization on grain boundaries in dilute nanocrystalline alloys
Effect of Sn microalloying and vacancies on diffusion of Zr in Aluminum
Enhancing radiation tolerance via defect engineering
Grain boundary migration during irradiation and oxidation of alloys
High Strength and Ductile, Single-Phase, Refractory Multi-Principle-Element Alloys (RMPEAs) by Theory-Guided Tailoring: Effects of Chemical Short-Range Order, Vacancies, and Hydrogen
How Alloying Elements Shape Vacancy-Induced Solute Clustering in Binary Magnesium Alloys
Hydrogen's Influence on Vacancy Diffusion in Metals: Inhibitor or Catalyst?
Influence of thermo-mechanical processing on ordering kinetics in 18 karat red gold alloy
Insights of Nano-Void Nucleation and Solute Aggregation in Magnesium Alloys Using Transition Interface Sampling
Investigating nanocavity formation kinetics in irradiated materials through elemental segregation
Irradiation-Enhanced Transport in Model Oxides: Insights from Isotopic Tracers and Atom Probe Tomography
Modeling the Potential Energy Landscape of Vacancies in Nickel Superalloys Using Atomistic Simulations and Machine Learning
Modelling the role of impurity trapping in excess vacancy evolution and its influence on age hardening behaviors in multicomponent aluminium alloys
Multiscale Modeling of Vacancy Trapping and Clustering Kinetics in Multicomponent Alloys
Nanoscale vacancy mapping in metals by four-dimensional scanning transmission electron microscopy (4D-STEM)
Positron annihilation spectroscopy in Mg and Mg-alloys
Quantifying Irradiation Damage with 4D-STEM
Stabilizing solute clusters in low-alloy steels: Effects of excess vacancies and impurity interactions
Time–temperature superposition for the spall strength of light metals with nonequilibrium vacancy concentrations
Vacancy-Driven Irradiation-Induced Amorphization and Crystallization in Nanostructured Materials
Vacancy-driven phase stability phenomena in ion irradiated alloys
Vacancy-Mediated Diffusion in Complex Materials Quantified with Machine Learning
Vacancy and self-interstitial radiation defects in fusion power plant materials and their effect on reactor operation.
Vacancy Evolution in Structural Alloys and High-Entropy Ceramics under Extreme Irradiation Conditions

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