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Meeting 2027 TMS Annual Meeting & Exhibition
Symposium Spectroscopic Methods and Analysis for Nuclear Energy Related Materials
Presentation Title Raman Spectroscopy of Lanthanides in LiCl-KCl Eutectic for Nuclear Energy Systems
Author(s) Jonathan Lizandro Ramos, Dev Chidambaram
On-Site Speaker (Planned) Jonathan Lizandro Ramos
Abstract Scope Pyroprocessing of spent nuclear fuel is a promising path that can close the nuclear fuel cycle by reprocessing actinides into new fuel and separating the parts that cannot be recycled such as lanthanides. This leads to a buildup of lanthanides in the molten salt over time in the electrorefining step. Understanding the coordination and speciation of dissolved lanthanide ions is necessary to understand and predict the chemical, thermochemical, and thermophysical properties of the salt. This work will discuss the use of Raman spectroscopy to investigate and understand structure and speciation of lanthanides at various concentrations in a LiCl-KCl eutectic salt. This work was supported by the US Nuclear Regulatory Commission under award 31310023M0036.
Proceedings Inclusion? Planned:

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Advancing Neutron Scattering Techniques for Nuclear Materials
Application of Synchrotron X-ray Absorption Spectroscopy to Nuclear Materials
Characterizing Nuclear Energy Related Materials with Laser Ablation Laser Ionization (LALI) Mass Spectrometry
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Determination of High Temperature Mechanical Properties of Nuclear Fuel Using Temperature Resonant Ultrasound Spectroscopy
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In-situ Raman Spectrometry of Passive Surface Layers on Stainless Steel
In-Situ UV–Vis Quantification of Chlorobasicity in Binary Molten Chlorides: A Spectroscopic Framework for Molten Salt Reactor Chemistry
Irradiation-damage Response of Stable Grain-boundary-decorated Nanocrystalline Multi-principal-element Alloy
Linking Atomic Structure to Engineering Performance in Refractory Materials for Fusion and Fission
Multimodal chemical imaging and microanalysis of intermetallic materials
NMR Spectroscopy of Zirconium Carbides after High-Temperature Hydrogen Exposure
Nuclear Materials Research using the Activated Materials Laboratory and the Advanced Photon Source
One dislocation, one pore at a time: Probing radiation damage in nuclear materials
Potential of atom probe tomography for mapping hydrogen isotopes in nuclear materials
Raman Spectroscopy of Lanthanides in LiCl-KCl Eutectic for Nuclear Energy Systems
Real-Time Spectroscopic Characterization of Molten Salt Systems Using Electrochemical–LIBS Data Fusion and Probabilistic Neural Networks
Surface-Sensitive X-ray Absorption Spectroscopy for Investigating Corrosion Mechanisms in Actinide Metals
Synchrotron-based high-{energy/temperature/strain/modality} characterization resources for nuclear materials research at NSLS-II
Three-Dimensional Characterization of Crack and Inclusion Networks in a Service-Exposed Baffle Former Bolt Using High-Energy X-Ray Microscopy
Understanding Temperature in Extreme Conditions

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