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Meeting MS&T25: Materials Science & Technology
Symposium Advancements in Molten Salt/Metal Technology in Energy Applications: From Atoms to Plants
Presentation Title Development of a Thermal Conductivity Model for Molten Salts Based on the Pair Distribution Function
Author(s) Jacob Numbers, Troy Munro, Tony Birri, Nick Termini, Isaac Walker, Tyler Hamm
On-Site Speaker (Planned) Isaac Walker
Abstract Scope While Gen IV molten salt nuclear reactors (MSR) present significant potential advantages, designing and licensing MSRs require increased predictability of salt behavior. A critical parameter for MSR thermal hydraulic design is the temperature and composition-dependent thermal conductivity of the molten salt. A model for molten salt thermal conductivity is being developed at BYU which uses short-range order structural information provided by the pair distribution function to estimate the mean free path of energy carriers. Based on the phonon gas model, the present method uses the measurable macroscopic specific heat capacity, sound velocity, and endmember properties to predict a molten salt mixture’s thermal conductivity as a function of temperature and composition. Comparisons to experimental measurements indicate applicability to salts ranging from unary alkali-halides to actinide-bearing mixtures, providing increasing modeling capability for MSRs. These results aim to advance the fundamental understanding of heat transfer in molten salts and liquids in general.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Computational Approach to Investigate the Role of Impurities on Corrosion Behavior in Molten Salt Reactors
Accurate Free Energy Simulations in Molten Salts with Machine Learning Potentials and High-Level Quantum Chemical Methods
Beyond proof of concept: the role of lab scale pilots in parallel to commercial operations
Development of a Thermal Conductivity Model for Molten Salts Based on the Pair Distribution Function
Electrochemical behavior of oxygen-evolving precious metal anodes in molten LiCl-Li2O electrolyte
EuCl3 mediated corrosion of Ni and Ni-20Cr Model Alloy in LiCl-KCl molten salt
Experimental calorimetry of heat capacity and mixing enthalpy of molten chloride salts
Fuel Salt Synthesis for the Molten Chloride Reactor Experiment: Scale-up, Operations, and Production Update
Laser-Spectroscopy Testbed for Impurity Monitoring in High-Temperature Reactors
Molten Salt Properties Capabilities at ORNL
Novel Al/Ti-Modified Ni-Mo-W-Cr Alloys for High Temperature Structural Applications in Molten Chloride Fast Reactors
Radiation-induced iodine chemistry in high-temperature molten salts
Separation of fission products from high-level waste salt via melt-crystallization
Synchrotron-Based X-ray Spectroscopy of Molten Salts
Testing Reference Electrodes in FLiNaZr Molten Salt
The Effect of Irradiation on the Densities of Chloride-Bearing Molten Salts
Towards the development of an inert anode for reprocessing of used nuclear fuel

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