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Meeting 2026 TMS Annual Meeting & Exhibition
Symposium Fracture and Deformation Across Length Scales: Celebrating the Legacy of William Gerberich
Presentation Title In search of stress-induced complexion transitions in nanocrystalline metals
Author(s) Maarten P. De Boer, Md Shariful Islam, Xipeng Li, Wen-Yu Chen, Sebastian Calderon, Elizabeth Dickey, Gregory Rohrer
On-Site Speaker (Planned) Maarten P. De Boer
Abstract Scope The thermodynamic phase of a material is determined by composition, temperature, and pressure. Grain boundaries also assume a thermodynamic phase, known as a complexion. In ceramic materials, complexions transition from one state to another depending on composition and temperature. In metals there is also evidence of complexion transitions. We have recently directly observed via high resolution scanning transmission electron microscopy (HRSTEM) a reversible temperature-induced solvent segregation to boundaries in a Au-Pt alloy. Complexion transitions that are governed by stress are predicted theoretically, but have not yet been observed in metals or ceramics. In turn, such transitions are likely to alter mechanical behavior. In this talk, I will describe our search for stress-induced complexions in this Au-rich Au-Pt alloy using a newly-developed nanomechanical test platform. The platform enables direct TEM observation under controlled temperature and stress, and simultaneously allows high-resolution thin film creep measurements of this nanocrystalline alloy.
Proceedings Inclusion? Planned:
Keywords Phase Transformations, Mechanical Properties, Characterization

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Stochastic Approach to Critical Energy Release Rate in Phase-Field Fracture Simulation
Bending Hard Phases to Gerberich’s Will
Deep Learning in Characterization of Nanoindentation Induced Acoustic Events
Ductile-to-brittle transition in quasicrystals across length scales
Effects of Grain Size on Plasticity Mechanisms of Nanocrystalline MgAl₂O₄ Spinel under Nanoindentation: Hall-Petch vs. Inverse Hall-Petch
Effects of Grain Size, Orientation, and Indentation Spacing on Nanoindentation Response in 1100 Aluminum
From the Titanic to nanopillars: brittle to ductile transitions as a function of temperature and size
Harnessing Machine Learning for Quantum-Accurate Predictions of Nonlinearities and Fracture in 2D Materials
In-situ HRTEM on atomic-scale plasticity in nanoscale materials
In search of stress-induced complexion transitions in nanocrystalline metals
Interface-Driven Strength and Fracture Behavior in Ni-Al Multilayers: Insights from Micromechanical Testing
Interrelations between the Fracture Toughness and Nanoindentation Derived Properties for Accelerated Alloy Screening
Linking the Dislocation Microenvironment to Properties in Metals and Alloys
Material Metrologies for Reliable Semiconductor Manufacturing
Measuring toughness at the microscale - a tribute to Bill Gerberich
Nanoindentation Combined with In-Situ SPM Imaging, and Later with TEM Imaging
New "Eyes and Ears" on the Origins of Friction from Two-Axis Nanoindentation
Observing Defects and Fracture in the TEM
Plasticity Effects and Fracture at the Microscale
Recent Advances on the Size Effect on Fracture Toughness of Materials: The Role of crack tip stress in explaining crack size and specimen size effects
Revealing the line-defect-based mechanisms of deformation-induced martensitic transformations
Role of Grain Boundary Slip Transfer on Deformation and Damage Behavior in Titanium
Spatial Statistics Framework for Detecting Strain Field Heterogeneity and Damage in Composite Adhesive Joints
Stress-Strain Relationship of Carbamazepine form III: From Nanoindentation to Micropillar Compression
The Stochastic Buckling of Geometrically-Imperfect Hemispherical Shells Exhibits a Similar Size Effect as the Strength of Brittle Solids
Yield points during indentation: what one small step can tell you

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