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Meeting 2026 TMS Annual Meeting & Exhibition
Symposium Local Chemical Ordering and Its Impact on Mechanical Behaviors, Radiation Damage, and Corrosion
Presentation Title Influence of Chemical Short-Range Ordering on Hydrogen Interaction in CoCrNi
Author(s) Eric Marchezini Mazzer, Livia Cupertino Malheiros, Sangchu Quan, David Silva, Francisco Gil Coury
On-Site Speaker (Planned) Eric Marchezini Mazzer
Abstract Scope Hydrogen embrittlement is a critical issue for alloys exposed to hydrogen-rich environments. In this study, we investigate the influence of chemical short-range ordering (CSRO) on hydrogen uptake and its impact on mechanical properties in equiatomic CoCrNi alloys. Samples were heat treated to induce varying degrees of CSRO. Hydrogen interaction was assessed using thermal desorption spectroscopy (TDS), revealing that increased CSRO affects H trapping and reduce the diffusivity. Tensile testing under hydrogen-charged conditions showed that alloys with pronounced CSRO exhibited reduced embrittlement compared to more chemically disordered counterparts. These results indicate that CSRO not only alters the trapping landscape for hydrogen but also enhances resistance to H-induced mechanical degradation. Our findings underscore the role of local chemical order as a possible parameter in designing CoCrNi-based alloys for hydrogen-tolerant applications.
Proceedings Inclusion? Planned:
Keywords Characterization, High-Entropy Alloys, Mechanical Properties

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

a-MCDFT: A Data-Driven Framework for Accelerated Discovery of Local Chemical Ordering in Complex Alloys
A Computational Thermodynamics Framework with Intrinsic Chemical Short-Range Order: New Developments in Ternary and BCC Systems with Intrinsic Chemical Short-Range Order
Atomic-Scale Structure of Zirconia: Formation of Metastable Polymorphs
Atomic Level Observation of Grain Boundary Phases With Icosahedral Order
Atomistic Insights into the Roles of Mechanical Strain and Chemical Ordering on Molten FLiNaK Salt Corrosion of NiCr Alloys
Can current interatomic potentials accurately reproduce observed local order?
Chemical Anisotropy Governs Radiation-Induced Defects in Refractory Multiple Principal Element Alloys
Chemical Disorder and Atomic Transport in Complex Oxides
Chemical Short-Range Order and Kinetics of Diffusive Relaxation
Chemical Short-Range Order and Radiation Resistance in High-Entropy Ceramics
Chemical Short-Range Order in Complex Alloys: From Fundamental Understanding to Property Control
Chemical Short-Range Order in High-Entropy Alloys: State of the Art
Combined Total Scattering and Physical Property Measurements for the Assessment of Local Order in Ni-Cr
Computational Studies of Thermodynamics and Ordering Kinetics of BCC/B2 Microstructures in W–Ta Refractory Alloys
Controlling Short-Range Ordering in Nanocrystalline High-Entropy Alloys Through Grain Boundary Segregation
Correlative 4D-STEM Mapping of Shear Band Evolution and Structural Heterogeneity in Metallic Glasses
Dislocation Motion Behaviors in Multi-Principal Element Alloys: Insights From Atomistic Simulations and Machine Learning
Effects of Short Range Order on Primary Passivation in Simple Alloys
Elastic Microstructure, Local Ordering, and Strain Fluctuations in Metallic Glasses
First-Principles Investigation of Cluster Size Effects on Oxide Adsorption in Binary Magnetic Alloys
From Short-Range to Long-Range Ordering: Unraveling Local Chemical Ordering Evolution in (CrCoNi)93Al4Ti2Nb MEA via Advanced 4D-STEM Diffuse Scattering Analysis
Grain Boundaries and Dislocations Can Amplify Local Chemical Ordering
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Improved Mechanical Behavior in Metastable Ti–50Nb via Oxygen-Induced Phase Evolution
In Situ Investigation of Ion Species-Dependent Irradiation Effects on Lattice Stability in RHEAs
Influence of Chemical Short-Range Ordering on Hydrogen Interaction in CoCrNi
Interpreting Short Range Order With Electron Microscopy
Kinetics of One-Step Solid-State Alloy Making: On the Local Chemistry at the Metal-Oxide Interface
Local Chemical Ordering Around Extended Defects in High-Entropy Alloys
Local Ordering Along Stacking Faults: Kinetic Aspects and Their Impact on Creep in Superalloys
Making Sense of the Noise: Differentiating Sources of Diffuse Electron Scattering Signals in Chemically Complex FCC Alloys and Why It Matters
Nonequilibrium Chemical Short-Range Order
Probing Short-Range Order in Concentrated Solutions via Nonlinear Ultrasonic Wave Propagation
Revisiting the Role of Chemical Order on Mechanical Properties of Ni-Cr Solid-Solution Alloy
Solute Cluster Strengthening in Mg-Ca-Zn Alloys
Study of Atomic Ordering in CrNi- and CoCrNi-Based Alloys Induced by Heat Treatments
Substantial Increase in Fracture Energy of Co30Cr40Ni30 Alloy: Role of Chemical Short-Range Order?
The Impact of Al on α' Precipitation in FeCrAl Alloys Under Thermal Aging and Irradiation
The Statistics of Defect Energetics and Their Effects on Transport Properties in Concentrated Solid Solutions
Thermodynamic nature of the local chemical ordering phenomenon
Toward Engineering Local Chemical Ordering: Experiments Integrated With Lightweight Atomistic Modeling
Tuning Short-Range Order in Refractory High-Entropy Alloys for Enhanced Passivation
Unravelling Entangled Local Strengthening Mechanisms in Face-Centered Cubic Multi-Principal Element Alloys
Unveiling Short-Range Ordering in Complex Alloys via Atom Probe Tomography: A Perspective on the History, Present and Future

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