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Meeting 2027 TMS Annual Meeting & Exhibition
Symposium Next Generation Electrometallurgical Technologies for Metal Extraction, Refining, and Recycling
Presentation Title A Rotating Porous Cathode Electrolytic Cell for Quasi-Continuous, Sustainable Iron Powder Production from Copper Smelting Dust
Author(s) Atharva Pandhare, Hao Zhou, Omid Mahdavi, Yan Wang, Adam Powell
On-Site Speaker (Planned) Omid Mahdavi
Abstract Scope Low-temperature alkaline electrolysis offers a low-energy, cost-effective pathway for sustainable iron powder production, yet limited by batch-style operation requiring frequent disassembly for mass production. Here, we developed an electrolytic cell featuring a rotating porous cathode, guided by numerical simulations, that enables quasi-continuous iron powder production using copper smelting dust as raw material and without cell disassembly. Over four consecutive feeding cycles, the system consistently delivered iron purity exceeding 95wt% and current efficiency above 91%, matching single-batch benchmarks and slightly outperforming static cells, while substantially improving operational throughput and stability. Techno-economic analysis and life cycle assessment further confirm the industrial viability of this approach, yielding a levelized cost of $520/ton hot-rolled coil (HRC) steel and greenhouse gas emissions of 1,653 kg CO2e/MT HRC—both favorable relative to conventional blast furnace technology. These results establish the rotating-cathode architecture as a scalable, economically competitive, and environmentally beneficial strategy for decarbonized industrial iron production.
Proceedings Inclusion? Planned:
Keywords Electrometallurgy, Iron and Steel, Extraction and Processing

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Rotating Porous Cathode Electrolytic Cell for Quasi-Continuous, Sustainable Iron Powder Production from Copper Smelting Dust
Carbon Emissions Assessment of Steelmaking Routes for 40Cr Steel
Closed-Loop Electrochemical Extraction and Recovery of Critical Minerals Using Low-Cost Open-Source Ion Exchange Membranes
Decarbonizing metal extraction through molten salt electrolysis with non consumable anodes
Electrometallurgy for Lithium Extraction and Processing
Electrons as Reductants: Transforming Metal Production through Electrometallurgy
Engineering Transition Metal Oxide Electrode for Direct Lithium Extraction from Aqueous Brines
Evidence of Silicon Production from Fluxed End-of-Life Photovoltaic Glass via Molten Oxide Electrolysis
High-Temperature Molten Salt Electrolysis for Sustainable Small-Molecule Chemical Synthesis
Liquid-Metal Bipolar Membrane for Electrochemical Recovery of Critical Metals in Molten Salts
Molten Salt Electrolysis for Iron Production: Progress Toward Decarbonized Ironmaking
Nordic Salt Cycle – Scaling a Molten Salt Process for Critical Mineral Recovery to Pilot
Recovery of Valuable Metals From Secondary Resources Using Molten Oxide Electrolysis
Thermodynamic and Experimental Investigation of In-Furnace Recycling of Electric Arc Furnace Dust
Three-Layer Electrorefining of Liquid Zn and Pb Held on/in Porous Holding Materials in Molten Chlorides

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