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Meeting MS&T25: Materials Science & Technology
Symposium Grain Boundaries, Interfaces, and Surfaces: Fundamental Structure-Property-Performance Relationships
Presentation Title Developments in XPS Surface Analysis: Femtosecond Laser Ablation Depth Profiling
Author(s) James Lallo, Tim Nunney, Richard White, Mark Baker
On-Site Speaker (Planned) James Lallo
Abstract Scope X-ray Photoelectron Spectroscopy [XPS] depth profiling is a widely employed analytical technique to determine the chemical composition of thin films, coatings and interfaces of multi-layered structures, due to its ease of quantification, good sensitivity and chemical state information. However, many organic and inorganic materials suffer from ion beam damage, resulting in incorrect chemical compositions to be recorded during the depth profile. A prototype XPS depth profiling instrument has been constructed that employs a femtosecond laser rather than an ion beam for XPS depth profiling purposes. This novel technique has shown the capability of eradicating chemical damage during XPS depth profiling for all initial inorganic, compound semiconductor and organic materials examined. The technique is also capable of profiling to much greater depths and is much faster than traditional ion beam sputter depth profiling. fs-LA XPS depth profile results will be shown for selected thin films, coatings, multilayer interfaces and oxidized surfaces.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

4D Observations of Grain Growth in Polycrystalline Alumina
An analysis of intergranular fracture in binary refractory alloys and the influence of segregation
Atomic and electronic structure of impurity-segregated grain boundaries in α-Al2O3
Atomistic Modeling Of Structure And Tritium Transport In Fe-Al-Cr Quasicrystal Phase
Clay-based Ceramics: a Material Full of Interfaces and Surfaces
Correlating Atomic Structure to Velocity of Grain Boundaries in Metal Oxides
Developments in XPS Surface Analysis: Femtosecond Laser Ablation Depth Profiling
Dislocation–Grain boundary interactions in bi-crystal and polycrystalline strontium titanate
Evidence for accelerated grain boundary diffusion during ultrafast firing (UHS) of alumina
Evolution of Metal Nanoparticles at Solid–Gas and Solid–Solid Interfaces: Segregation Reactions in Ceramic Matrices
Finding the ‘right’ boundary: grain boundary-stress fundamental zones
Grain Boundary Segregation and Conductivity in 3YSZ
In-situ Characterization of Interface Evolution during Zinc Electrodeposition in Alkaline Electrolytes
Influence of the Duplex CoTiO3-TiO2 Microstructure on the Nucleation and Growth of Entropy-Stabilized CoTi2O5
Local Multimodal Electro-Chemical-Structural Characterization of Solid-Electrolyte Grain Boundaries
Neural-Network Potential Based on Trainable Descriptor for Modeling Complex Interfacial Structures and Properties
On the soda-lime glass surface and its interactions with water
Phase Field Modeling of Microstructure-Dependent Effective Electrical Conductivity in Battery Electrodes
Polarization Behavior of Electrical Conductors and Its Dependence on the Microstructure
Preliminary Investigation of Metal-SiC Interface Behavior via Deposition of Mo and W for High-Temperature Applications
Quantifying Surface and Grain-Boundary Energies in Yttria-stabilized Zirconia: Influence of Grain Size and Sintering Conditions
Sub-grain Boundary Dynamics During Early-Stage Recrystallization in High-Purity Aluminum
Tuning Hardness and Fracture Toughness of SPS-Sintered MgAl2O4 + YSZ via Na Doping and Field-Assisted Microindentation
Using Interface Layer Quantities to Compute Unambiguous Thermodynamic Quantities from Atomic Data Sets

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