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Meeting 2027 TMS Annual Meeting & Exhibition
Symposium Next Generation Electrometallurgical Technologies for Metal Extraction, Refining, and Recycling
Presentation Title High-Temperature Molten Salt Electrolysis for Sustainable Small-Molecule Chemical Synthesis
Author(s) Xiaofei Guan
On-Site Speaker (Planned) Xiaofei Guan
Abstract Scope Historically, high-temperature electrometallurgy and chemical synthesis have operated on different scales: one focused on bulk extraction of metals, and the other on molecular transformations. However, the rise of electrochemical synthesis has created a unique convergence point. This presentation explores how the high-temperature electrometallurgical technologies based on molten metal-salt systems are leveraged to drive chemical synthesis and address significant challenges in catalysis. This talk will introduce reactive metal-mediated cycles established in the molten metal-salt systems to facilitate some key reactions, including the coking-free dry reforming of methane to produce syngas (a mixture of hydrogen and carbon monoxide) and the natural gas decomposition to produce hydrogen, ethylene, and carbon. In addition, clean electricity can be used to power the processes to further reduce carbon emissions. Overall, applying high-temperature electrometallurgical technologies to sustainable chemical synthesis represents a promising direction and will motivate further research and development.
Proceedings Inclusion? Planned:
Keywords Electrometallurgy, Extraction and Processing, Sustainability

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Rotating Porous Cathode Electrolytic Cell for Quasi-Continuous, Sustainable Iron Powder Production from Copper Smelting Dust
Carbon Emissions Assessment of Steelmaking Routes for 40Cr Steel
Closed-Loop Electrochemical Extraction and Recovery of Critical Minerals Using Low-Cost Open-Source Ion Exchange Membranes
Decarbonizing metal extraction through molten salt electrolysis with non consumable anodes
Electrometallurgy for Lithium Extraction and Processing
Electrons as Reductants: Transforming Metal Production through Electrometallurgy
Engineering Transition Metal Oxide Electrode for Direct Lithium Extraction from Aqueous Brines
Evidence of Silicon Production from Fluxed End-of-Life Photovoltaic Glass via Molten Oxide Electrolysis
High-Temperature Molten Salt Electrolysis for Sustainable Small-Molecule Chemical Synthesis
Liquid-Metal Bipolar Membrane for Electrochemical Recovery of Critical Metals in Molten Salts
Molten Salt Electrolysis for Iron Production: Progress Toward Decarbonized Ironmaking
Nordic Salt Cycle – Scaling a Molten Salt Process for Critical Mineral Recovery to Pilot
Recovery of Valuable Metals From Secondary Resources Using Molten Oxide Electrolysis
Thermodynamic and Experimental Investigation of In-Furnace Recycling of Electric Arc Furnace Dust
Three-Layer Electrorefining of Liquid Zn and Pb Held on/in Porous Holding Materials in Molten Chlorides

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