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Meeting MS&T25: Materials Science & Technology
Symposium Grain Boundaries, Interfaces, and Surfaces: Fundamental Structure-Property-Performance Relationships
Presentation Title Polarization Behavior of Electrical Conductors and Its Dependence on the Microstructure
Author(s) Deborah D.L. Chung
On-Site Speaker (Planned) Deborah D.L. Chung
Abstract Scope Electrical conductors (carbons and metals) undergo polarization due to carrier-atom interaction, which involves a small fraction of the carriers and mainly occurs at heterogeneities such as grain boundaries. The greater is the prior cold work by rolling, the higher is the permittivity. The permittivity is colossal, though the polarization is low. The polarization hinders conduction, thereby increasing the apparent resistance. The depolarization is less significant than the prior polarization - hence electrical asymmetry. The AC capacitance decreases to zero upon short circuiting (discharge), and is restored upon subsequent open circuiting (self-charge), as shown for single carbon fiber. By offsetting the start time for discharge-charge cycling for various single fibers, nonstop electrical energy is released. The DC electret voltage also decreases to zero upon short circuiting, and is restored upon subsequent open circuiting. The voltage increases with cold rolling, with the positive end of the voltage being where the rolling starts.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

4D Observations of Grain Growth in Polycrystalline Alumina
An analysis of intergranular fracture in binary refractory alloys and the influence of segregation
Atomic and electronic structure of impurity-segregated grain boundaries in α-Al2O3
Atomistic Modeling Of Structure And Tritium Transport In Fe-Al-Cr Quasicrystal Phase
Clay-based Ceramics: a Material Full of Interfaces and Surfaces
Correlating Atomic Structure to Velocity of Grain Boundaries in Metal Oxides
Developments in XPS Surface Analysis: Femtosecond Laser Ablation Depth Profiling
Dislocation–Grain boundary interactions in bi-crystal and polycrystalline strontium titanate
Evidence for accelerated grain boundary diffusion during ultrafast firing (UHS) of alumina
Evolution of Metal Nanoparticles at Solid–Gas and Solid–Solid Interfaces: Segregation Reactions in Ceramic Matrices
Finding the ‘right’ boundary: grain boundary-stress fundamental zones
Grain Boundary Segregation and Conductivity in 3YSZ
In-situ Characterization of Interface Evolution during Zinc Electrodeposition in Alkaline Electrolytes
Influence of the Duplex CoTiO3-TiO2 Microstructure on the Nucleation and Growth of Entropy-Stabilized CoTi2O5
Local Multimodal Electro-Chemical-Structural Characterization of Solid-Electrolyte Grain Boundaries
Neural-Network Potential Based on Trainable Descriptor for Modeling Complex Interfacial Structures and Properties
On the soda-lime glass surface and its interactions with water
Phase Field Modeling of Microstructure-Dependent Effective Electrical Conductivity in Battery Electrodes
Polarization Behavior of Electrical Conductors and Its Dependence on the Microstructure
Preliminary Investigation of Metal-SiC Interface Behavior via Deposition of Mo and W for High-Temperature Applications
Quantifying Surface and Grain-Boundary Energies in Yttria-stabilized Zirconia: Influence of Grain Size and Sintering Conditions
Sub-grain Boundary Dynamics During Early-Stage Recrystallization in High-Purity Aluminum
Tuning Hardness and Fracture Toughness of SPS-Sintered MgAl2O4 + YSZ via Na Doping and Field-Assisted Microindentation
Using Interface Layer Quantities to Compute Unambiguous Thermodynamic Quantities from Atomic Data Sets

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