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Meeting MS&T25: Materials Science & Technology
Symposium Understanding Corrosion-Related Cracking
Presentation Title Effect for hydrogen embrittlement and sulfide stress cracking in HSLA carbon steel when exposed to H2S environments
Author(s) Homero Castaneda, Raymundo Case, Lianlian Liu
On-Site Speaker (Planned) Homero Castaneda
Abstract Scope Different harsh conditions limit the use of high-strength low-alloy carbon steels in upstream oil production due to corrosion, mechanical loading, and hydrogen permeation risks. This talk discusses how steel grade C110 performs under combined exposure to corrosion precursors (H₂S, pH, NaCl), mechanical stress, and hydrogen permeation. Using electrochemical methods like hydrogen permeation and electrochemical impedance spectroscopy (EIS), we studied hydrogen embrittlement mechanisms. Hydrogen permeation increases with higher H₂S concentrations, lower pH, and reduced NaCl. An adsorption isotherm is developed to understand how H₂S affects hydrogen permeation through hydrogen reduction or absorption. Notched tensile slow strain rate tests quantify susceptibility to sulfide stress cracking (SSC). Results show H₂S significantly impacts SSC susceptibility via hydrogen embrittlement. Additionally, higher NaCl concentrations lead to increased pit density, facilitating crack initiation and reducing fracture energy, thus increasing SSC risk. Understanding these correlations helps characterize steel performance in corrosive environments.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Effect for hydrogen embrittlement and sulfide stress cracking in HSLA carbon steel when exposed to H2S environments
Effect of deposit chemistry on the stress corrosion cracking susceptibility of CMSX-10 at 550°C and 700°C
Environmentally Assisted Cracking in Ni-based Superalloys
First Experimental Evidence of Liquid Metal Embrittlement of Two Titanium Alloys by Lithium
Impact of alloy composition and liquid chemistry on cracking susceptibility of fusion candidate structural materials in liquid lithium
Influence of Cold Work on Environmentally Assisted Cracking of a Single Crystal Nickel Based Superalloy CMSX-4
Influence of crack environment pH on Corrosion Fatigue Crack Growth in Aerospace Aluminum Alloys
Misch Metal-Induced Corrosion Resistance Enhancement in Ti-Based Amorphous Powders
Phase-Field Modeling of Oxidation and Cracking in Environmental Barrier Coatings
Pre-crack Degradation Pathways of NaCl-assisted Hot Corrosion of a 2nd Generation Ni-based Superalloy
Predicting Environmentally Assisted Fatigue Crack Growth in AA7075 Using Machine Learning Approaches
Reduced graphene oxide as a protection layer for Al
Study of the Role of Hydrogen in the Cold-cracking of As-cast 7xxx Aluminum Alloys
Understanding Pit Morphological Features that Initiate SCC in SS304H used for Nuclear Waste Storage Canisters
Understanding the ability of combined effects corrosion fatigue accelerated testing to properly reflect in-service performance for aerospace Al alloys
Understanding the effect of tempering on sulfide stress cracking response in high-strength casing steel
Understanding the Role of Microstructure on the Sub Critical Crack Growth Rate and Crack Path in Pipeline Ferritic Stainless Steels
Understanding the Role of Microstructure on the Sub Critical Crack Growth Rate and Crack Path in Pipeline Ferritic Stainless Steels

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