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Meeting 2027 TMS Annual Meeting & Exhibition
Symposium Interstitial–Metal Interactions: The Outsized Role of Small Atoms
Presentation Title Tracking interstitial hydrogen atoms in metals by using atom probe tomography
Author(s) Eason Yi-Sheng Chen
On-Site Speaker (Planned) Eason Yi-Sheng Chen
Abstract Scope Hydrogen embrittlement threatens the reliability of structural steels required for safe hydrogen transport, storage and use. This presentation introduces our recent efforts to visualize and understand how interstitial hydrogen atoms distribute within metallic microstructures, and how their trapping governs embrittlement resistance. Using cold-drawn high-strength pearlitic steels as a model system, we combine atom probe tomography with cryogenic sample transfer, hydrogen-charging mechanical testing and transmission electron microscopy to directly correlate hydrogen localization with deformation substructures and fracture behavior. Our results demonstrate that specific dislocation configurations can act as strong hydrogen traps, reducing the amount of mobile hydrogen available to promote cracking. These observations validate hydrogen trapping as an effective strategy for mitigating embrittlement, while providing mechanistic insight into microstructure-property-processing relationships in hydrogen-containing metals. The findings offer guidance for designing steels with improved durability, particularly for gas pipeline applications central to the emerging hydrogen economy and other critical hydrogen-facing structural components globally.
Proceedings Inclusion? Planned:
Keywords Characterization, Iron and Steel, High-Entropy Alloys

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A First Principles Study on the Role of Grain Boundaries in the Oxidation of Refractory Metals
A Phonon-Based Approach for Predicting the Heat of Transport of Interstitial Hydrogen in Tungsten
Atomic- to nanoscale mechanisms driving carburization-enhanced corrosion resistance and strength in AM 316L
Bubble Growth from Interstitial Helium in Palladium: An Atomistic Study
Controlling Interstitial Impurities to Improve Manufacturability of Refractory Multi-Principal-Element Alloys
Coupled Effects of Hydrogen, Grain Boundaries, and Free Surfaces on Dislocation Activity in Polycrystalline Nickel
Data-Driven Diffraction Libraries for Identifying Metastable States in Complex BCC Refractory Alloys
Dislocation interactions in MoNbTi and their role mediating low temperature ductility
Effects of Heat Treatment and Hydrogen Exposure on Fracture Resistance and Fatigue Crack Growth in 15-5 PH Stainless Steel
Effects of Interstitial Oxygen on the Grain-scale Deformation Behavior of Vanadium
Effects of Oxygen Interstitials on Vacancy Mobility in Refractory Metals and Alloys
Fracture Mechanics Evaluation of High-Pressure Torsion-Processed DSN9 Steel for Hydrogen–Natural Gas Pipeline Applications
Hydrogen-Vacancy Co-Segregation and Fast Grain-Boundary Hydrogen Diffusion in Copper
Hydrogen charging at room temperature to reduce dislocations in steel with residual stresses
Impact of Surface Oxide on Hydride Formation in Niobium and Tantalum
Influence of Hydrogen on Disconnection Energetics and Grain Boundary Migration in Nickel
Interstitial Diffusion in Grain Boundaries
Interstitial effects on temperature-dependent critical stress and dislocation glide of screw and edge dislocations in tantalum
Interstitial oxygen as a design platform to redefine strength-ductility relations in refractory high-entropy alloys
Microstructure-Controlled Hydrogen Trapping and TiH₂-Assisted Comminution of Ti-6Al-4V Machining Chips
Multi-time-scale analysis of strain rate sensitivity for understanding carbon-induced dynamic strain aging in Fe-Cr-Ni austenitic stainless steel
Oxygen-mediated phase decomposition in group IV–Nb refractory alloys
Predicting Interstitial Elements in Refractory Complex Concentrated Alloys
Segregation-assisted deformation twinning in face-centered cubic metals
Small Atoms, Large Effects: Minor-Element Interactions in Additively Manufactured ODS Superalloys
Spatial Relocalization of Hydrogen in Metals through Acoustic Wave Excitations
Stress- Driven Interstitial Phase Transformation in Metals
The effect of hydrogen concentration on the monotonic and cyclic deformation behavior of <001> oriented pure nickel single crystal
Thermodynamics and Kinetics of Interstitials in TiZrHfNbTa Refractory High-Entropy Alloys
Time-scale Competition of Hydrogen–Defect Interactions: A Phase–Field Crystal Study
Tracking interstitial hydrogen atoms in metals by using atom probe tomography
Tritium Transport in Tungsten for fusion energy applications: from interstitial behavior to Plasma-Facing Component Performance and Implications for the tritium Fuel Cycle
 The Role of Precipitation on Hydrogen Susceptibility of Nickel-based Alloy 725 

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