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Meeting 2027 TMS Annual Meeting & Exhibition
Symposium Electronic Packaging and Interconnection Materials IV
Presentation Title Effects of Bi and In Additions on Cu Interfacial Reactions in Medium-Temperature Lead-Free Solders
Author(s) Hung-Chi Tseng, Albert T. Wu
On-Site Speaker (Planned) Hung-Chi Tseng
Abstract Scope Advanced electronic packaging requires solder alloys with reduced processing temperatures and stable interfacial reactions. In this study, Bi and In were added to the Sn-Ag-Cu system to develop Sn-Ag-Cu-In-Bi medium-temperature lead-free solders. The effects of Bi and In on melting behavior, phase formation, thermal aging stability, and Cu/solder interfacial reactions were investigated. Differential scanning calorimetry, X-ray diffraction, electron probe microanalysis, and cross-sectional microscopy were used for characterization. The results showed that In and Bi effectively reduced the melting temperature of SAC-based solders and slower the growth of intermetallic compound at the interface. After reflow, the interfacial layer was mainly Cu6(Sn,In)5, while limited Cu3(Sn,In) formation was observed after aging. Kinetic analysis showed that Bi-In addition influenced IMC growth behavior, suggesting the importance of composition control for interfacial stability.
Proceedings Inclusion? Planned: TMS Journal: Journal of Electronic Materials
Keywords Electronic Materials, Joining, Solidification

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

3D X-ray Imaging and Defect Detection for Various Interconnects in Advanced Packaging
3D X-ray Imaging and Physics-based Simulation of 3D Defect Evolution in BGA Solder Joints under Thermal Cycling
A Three-Step Simultaneous Cutting & Chamfering (Dicing) Ultrafast-Laser Process for Reliable Singulation of Thin Amorphous Glass Disks: The Role of Wafer-Grade Vacuum Chucking and Direct-Drive Rotary Motion
Achieving Fluxless Bonding of Pure Indium TIM via Silver Metallization for Heat Dissipation in HPC Packaging
Crystallinity-Gradient Co–P Metallization for Rapid Co–Sn Full-IMC Interconnects
Development of Sn–In–Ag Composite Solder using Transient Liquid Phase Bonding
Effect of Ag Addition on the Microstructural Evolution and Bonding Behavior of Cu–Ag Alloy Thin Films
Effect of Cu Processing Conditions on the high-temperature stability and Thermal Properties of Cu Sintered Spacers
Effect of Grain Structure on Low-Temperature Ag-Cu Heterogeneous Direct Bonding Without CMP
Effects of Bi and In Additions on Cu Interfacial Reactions in Medium-Temperature Lead-Free Solders
Electric-field assisted formation of stable one-dimentional SAC305 solder microparticle interconnects
Electromigration Behavior and Dynamic Mechanical Response of Indium-Modified Sn/Ag/Cu Solder Joints.
Electromigration behavior of Cu₃Sn interconnects fabricated via Solid-Liquid Interdiffusion
Evolution of Microstructure and Micro-hardness in Room-Temperature Aged Sn-5wt%Bi Alloys: A Quasi In-Situ Study on Precipitation Kinetics
Interfacial Stability and Reliability of Sn–3.5Ag Solder Joints with FeCoNiMn Diffusion Barriers
Liquid/Solid interfacial reactions between the Sn solder and Cu-Be alloy (Alloy 25) with the Ni electroplating layer
Long-Term Thermal Reliability and Microstructural Evolution of Near-Eutectic Sn-Bi-Ag-Sb/Cu Solder Joints
Low-Temperature Rapid Formation and Diffusion Mechanism of Co-Sn Full-IMC Interconnects for Power Electronic Packaging
Microstructure-Controlled Bonding and Thermal Stability in Planarized Ag–Cu Direct Bonding
Microstructure-Controlled Sn-In/Sn-Bi-Ag Composite Solders for Low-Temperature High-Toughness Packaging
Microstructure evolution and crack propagation in Sn-Ag-Cu-Bi solder joints during harsh thermal cycling
Multi-Layer Energy Transfer and Interfacial Heterogeneity in Ultrasonically Welded Ni/Al Lamellar Structures for EV Battery Tab Applications
Non-destructive Characterization of High Bandwidth Memory
Position-Dependent Cracking Behavior of Micro-Solder Joints on AlN Ceramic Substrates under Thermal Cycling
Solder in Vibration: Predicting Solder Joint Reliability during High Cycle Fatigue
Solderability and Interconnect Performance in Additively Manufactured Flex Cables
Stress and Temperature Driven Crossover in Deformation Mechanisms in Cu-based Thin Films
Suppressing Sn Whisker Growth by Interlayer Engineering: Effect of Residual Stress, Alloying and Interface Chemistry
Thermal Transport and Reliability of Indium–Diamond Composite Paste for Advanced Packaging Applications
Thermomechanical Design-Space Quantification of Direct Cu–Cu Bonded Interconnect Geometry and Population in 3D Stacked Dies
X-ray Laminography for Defect Characterization in 3D Heterogeneous Integrated Packages

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