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Meeting 2026 TMS Annual Meeting & Exhibition
Symposium Cutting-Edge Characterization and Electrochemical Techniques for Unraveling Corrosion Phenomena
Presentation Title Real-Time Atomic-Scale Imaging of Defect-Driven Oxidation Under Reactive Gases
Author(s) Guangwen Zhou
On-Site Speaker (Planned) Guangwen Zhou
Abstract Scope Understanding how reactive gases drive atomic-scale oxidation is vital for developing corrosion-resistant alloys. Using in-situ environmental transmission electron microscopy (E-TEM) with atomic resolution, we directly capture the real-time structural evolution during oxidation in various reactive gas environments. Our observations show that oxide growth begins with point defect injection at the gas/oxide interface, which subsequently facilitates ion transport across the oxide layer. Crucially, different oxidants (O₂, H₂O, CO₂) generate distinct defect formation pathways and growth modes, highlighting the central role of gas chemistry in oxidation kinetics and interfacial behavior. This atomic-scale visualization of gas–solid reactions provides essential input for atomistic modeling, enabling a mechanistic understanding of oxide formation and degradation. By revealing how gas composition governs defect injection and transport, the combined in-situ imaging and modeling approach offers fundamental insights for predictive oxidation modeling and guides the rational design of oxidation-tolerant materials.
Proceedings Inclusion? Planned:
Keywords Characterization, Environmental Effects,

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Advanced Modeling Techniques for Efficient Discovery of Corrosion Phenomena
Application of Cutting-edge Materials Characterization Techniques to Understanding Stress Corrosion Cracking
Atomic-scale Understanding of Cu Effect on Mechanical, Antibacterial, and Corrosion Properties of Ultrahigh-strength Maraging Stainless Steel
Characterizing the mechanisms controlling localized corrosion of steel in concrete
Combined hydrogen permeation based potentiometry and electrochemical impedance spectroscopy technique to measure cathodic oxygen reduction kinetics at an organic coating/iron interface
Evaluating Passive Film Properties of Fe-Based Metallic Glasses for Enhanced Corrosion Resistance
Evaluation of SS316 Corrosion in a Flowing LiCl-KCl Environment with Real-Time Electrochemical Monitoring
Gathering Actionable Corrosion Data for Light Water Reactors and Molten Salt Reactors
Localized Hydrogen Irradiation of Metals Produced by Focused Ion Beam - Scanning Electron Microscope
Mapping the heterogeneous charge transport during oxidation of metals containing nanoscale metal inclusions with 4DSTEM and APT
Multimodal characterization of material degradation in nuclear environments
Non-Destructive Characterization of Metal-Coating Interface Revealing Corrosion Beneath the Coating
Perspectives on the development of oxidation-resistant alloys for Advanced Ultra-Supercritical power plants
Real-Time Atomic-Scale Imaging of Defect-Driven Oxidation Under Reactive Gases
Revisiting Transpassivity with a new lens: Transpassive corrosion mechanisms in Ni probed with in situ respirometry coupled electrochemical polarization
Scanning Kelvin Probe Techniques for Unraveling Corrosion Phenomena
Uncovering Atomic Scale Corrosion and Oxidation Mechanisms in Materials: Insights from Cryogenic Atom Probe Tomography and Atomic Force Microscopy
Understanding the Influence of Secondary Phase Particles on Localized Corrosion of Al A356 Alloy to Enable an Increased Use of Recycled Al
Whole-surface EBSD mapping for 1:1 correlation of grain structure and corrosion initiation

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