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Meeting MS&T25: Materials Science & Technology
Symposium Understanding and Mitigating High Temperature Corrosion Processes Through Synergistic Integration of Experimental, Computational and Manufacturing Techniques
Presentation Title Phase field informed Poisson-Nernst-Planck model for corrosion in molten salt environments
Author(s) Chaitanya V. Bhave, Parikshit Bajpai, Mauricio Tano Retamales, Samuel Austin Walker
On-Site Speaker (Planned) Chaitanya V. Bhave
Abstract Scope Molten salt reactors (MSRs) are an advanced nuclear technology with promising attributes such as inherent safety, high thermal efficiency, and the ability to operate at high temperatures. In MSRs, the fuel is dissolved in a halide salt and interacts with reactor materials leading to corrosion which can significantly impact reactor performance, safety and longevity. Effective modeling of corrosion and associated processes, such as leaching, deposition, and chemical species transport, is necessary to ensure safe and reliable operation of MSRs. Since corrosion is an electrochemical process, the Poisson-Nernst-Planck (PNP) model, combined with Butler-Volmer kinetics, has been implemented into MOOSE. A crucial aspect of these models is capturing the time-dependent interfacial flux of reactive elements from alloy to molten salt. This work discusses a multiscale approach, coupling phase-field method with the PNP model, to accurately capture the microstructural effects on the interfacial currents and their impact on macroscale corrosion modeling.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

AI-Driven Multiscale Computational Framework for Corrosion-Induced Degradation of High Temperature Alloys
Development of Low Temperature Sulphidation Resistant Coatings in Aerospace Environments
Discovering mappings between thermodynamic states in metal oxidation using machine learning
Evaluating CMAS-Coating Interactions for Jet Engine Applications
High-Temperature Corrosion Challenges of Wrought Alloys in Extreme Environments
Impact of water vapor and hydrogen on oxidation behavior of chromia-forming Ni-based alloys
Modeling premature breakaway oxidation of ferritic stainless steels above 850°C
Novel corrosion resistant coatings working with high-temperature corrosion obtained using FA- charges
Phase field informed Poisson-Nernst-Planck model for corrosion in molten salt environments
Predicting Internal to External Oxidation in High-Temperature Ni-Cr Alloys Using a CALPHAD-Informed Phase-Field Model
Understanding Compositional Effects on the Oxidation Behavior of Binary Nb-Ti Alloys

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